| Synthesis and Crystal Structure of a Novel Mixed Nido-like and Half-open Cubane-like Cluster [(n-Bu)_4N]_3[MoS_4Cu_5Br_6] |
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| 引用本文： | 刘泉,徐庆锋,张勇,陈金香,周志峰,郎建平. Synthesis and Crystal Structure of a Novel Mixed Nido-like and Half-open Cubane-like Cluster [(n-Bu)_4N]_3[MoS_4Cu_5Br_6][J]. 中国化学, 2002, 20(12): 1602-1607. DOI: 10.1002/cjoc.20020201225 |
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| 作者姓名： | 刘泉 徐庆锋 张勇 陈金香 周志峰 郎建平 |
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| 作者单位： | LIU，Quan XU，Qing-Feng ZHANG，Yong CHEN，Jin-Xiang ZHOU，Zhi-Feng LANG，Jian-Ping Department of Chemistry and Chemical Engineering，Suzhou University，Suzhou，Jiangsu 215006，China |
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| 基金项目： | theKeyLaboratoryofOrganicChemistryofJiangsuProvince (No .KJS0 1017)andtheStateKeyLaboratoryofCoordinationChemistryofNanjingUniversity |
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| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｃｈｅｍｉｓｔｒｙｏｆｔｈｅｔｈｉｏｍｅｔａｌｌａｔｅａｎｉｏｎｓｉｓｃｕｒｒｅｎｔｌｙａｓｕｂｊｅｃｔｏｆｉｎｔｅｎｓｅｉｎｔｅｒｅｓｔｄｕｅｔｏｔｈｅｉｒｒｉｃｈｓｔｒｕｃｔｕｒａｌｄｉ ｖｅｒｓｉｔｙ ,1 8ｔｈｅｉｒｒｅｌｅｖａｎｃｅｔｏｉｎｄｕｓｔｒｉａｌｃａｔａｌｙｔｉｃｐｒｏｃｅｓｓ9,10ａｎｄｍｅｔａｌｌｏｅｎｚｙｍｅｓ ,11,12 ａｎｄｔｈｅｉｒｐｏｔｅｎｔｉａｌｕｔｉｌｉｔｙａｓｎｏｎ ｌｉｎｅａｒｏｐｔｉｃａｌｍａｔｅｒｉａｌｓ .13 16Ｗｅｈａｖｅｒｅｐ…
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Synthesis and Crystal Structure of a Novel Mixed Nido-like and Half-open Cubane-like Cluster [(n-Bu)_4N]_3[MoS_4Cu_5Br_6] |
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| LIU,Quan XU,Qing-Feng ZHANG,Yong CHEN,Jin-Xiang ZHOU,Zhi-Feng LANG,Jian-Ping. Synthesis and Crystal Structure of a Novel Mixed Nido-like and Half-open Cubane-like Cluster [(n-Bu)_4N]_3[MoS_4Cu_5Br_6][J]. Chinese Journal of Chemistry, 2002, 20(12): 1602-1607. DOI: 10.1002/cjoc.20020201225 |
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| Authors: | LIU Quan XU Qing-Feng ZHANG Yong CHEN Jin-Xiang ZHOU Zhi-Feng LANG Jian-Ping |
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| Affiliation: | LIU,Quan XU,Qing-Feng ZHANG,Yong CHEN,Jin-Xiang ZHOU,Zhi-Feng LANG,Jian-Ping Department of Chemistry and Chemical Engineering,Suzhou University,Suzhou,Jiangsu 215006,China |
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| Abstract: | Reaction of (NH4)2MoS4 with [Cu(MeCN)4] (BF4) and (n‐Bu)4NBr in CH2Cl2 afforded a new hexanuclear cluster [(n‐Bu)4N]3[MoS4Cu5Br6] (1). 1 crystallizes in the monoclinic system, space group P21/c, with lattice parameters a = 1.17383(4) nm, b = 2.40136(4) nm, c = 2.64112(5) nm, β = 94.2020(5)°, V = 7.4247(5) nm3 and Z = 4. The structure of the [MoS4Cu5Br6]3‐ trianion of 1 is composed of one nido‐like [MoS3Cu3] core and one half‐open cubane‐like [MoS3Cu3Br] core, which are interconnected by sharing the same MoSCuS plane. The MoCu distances vary in the range of 0.2622(6)‐0.2692(5) nm. |
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| Keywords: | molybdenum cluster copper cluster sulfide cluster crystal structure |
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