| Synthesis and Characterization of Ethylthioethylcyclopenta-dienyl Organolanthanide Complexes:Cp_2~(Th)LnCl(Ln=Gd,Dy),Cp_2LnCp~(Th)(Ln=Yb,Sm,Dy,Y) and Cp~(Th)ErCl_2·2THF |
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| 引用本文： | 朱铭,张丽蓓,陈应华,周锡庚,蔡瑞芳,翁林红.Synthesis and Characterization of Ethylthioethylcyclopenta-dienyl Organolanthanide Complexes:Cp_2~(Th)LnCl(Ln=Gd,Dy),Cp_2LnCp~(Th)(Ln=Yb,Sm,Dy,Y) and Cp~(Th)ErCl_2·2THF[J].中国化学,2004(9). |
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| 作者姓名： | 朱铭 张丽蓓 陈应华 周锡庚 蔡瑞芳 翁林红 |
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| 作者单位： | Department of Chemistry，Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials，Fudan Uni-versity，Shanghai 200433，China，Department of Chemistry，Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials，Fudan Uni-versity，Shanghai 200433，China，Department of Chemistry，Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials，Fudan Uni-versity，Shanghai 200433，China，Department of Chemistry，Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials，Fudan Uni-versity，Shanghai 200433，China State Key Laboratory of Organometallic Chemistry，Shanghai Institute of Organic Chemistry，Chinese Academy of Sciences，Shanghai 200032，China，Department of Chemistry，Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials，Fudan Uni-versity，Shanghai 200433，China，Department of Chemistry，Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials，Fudan Uni-versity，Shanghai 200433，China |
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| 基金项目： | the National Natural Science Foundation of China and the Research Funds of Excellent Young Teacher and the New Century Distinguished Scientist of National Education Ministry of China. |
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| 摘 要： | Introduction Functional substituted cyclopentadienyl organolan-thanide complexes continue to attract considerable at-tention because these donor-functionalized side chains can increase the stability of highly reactive organolan-thanide complexes by forming the additional in-tramolecular chelating coordination with the central metal, and for early lanthanide complexes, the enhanced stability offers the opportunity to explore the reactivity of the remaining ligands.1-4 In addition, the in-tramol…
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