| Study on Electrochemical Copolymerization of Aniline and 3-Methylthiophene in HMIMBF4 Ionic Liquid and Its Properties |
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| 作者姓名： | 张爱健 张贵荣 杨广达 敖凤国 陆嘉星 |
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| 作者单位： | Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Deparement, East China Normal University, Shanghai 200062, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20573037） and the Natural Science Foundation of Shanghai （No. 05JC 14070）. |
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| 摘 要： | Electrochemical polymerization of aniline and 3-methylthiophene has been accomplished in 1-methylimidazium tetrafluoroborate （HMIMBF4） ionic liquid. Homopolymer and copolymers of aniline and 3-methylthiophene were obtained successfully. The copolymer was studied by cyclic voltammetry and electrochemical impedance spectroscopy. The formation of copolymer has been confirmed by FT-IR and UV spectra. The atomic force microscope （AFM） was used for microstructural analysis. Both the homopolymer and the copolymer had the catalytic activity for the hydroquinone.
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| 关 键 词： | 苯胺 电化学共聚合 3-甲基噻吩 HMIMBF4离子液体 氢醌 导电性质 |
| 修稿时间： | 2006-09-122006-11-22 |
Study on Electrochemical Copolymerization of Aniline and 3-Methylthiophene in HMIMBF4 Ionic Liquid and Its Properties |
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| ZHANG Ai-Jian, ZHANG Gui-Rong,YANG Guang-Da, AO Feng-Guo,LU Jia-Xing.Study on Electrochemical Copolymerization of Aniline and 3-Methylthiophene in HMIMBF4 Ionic Liquid and Its Properties[J].Chinese Journal of Chemistry,2007,25(3):268-271. |
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| Authors: | ZHANG Ai-Jian ZHANG Gui-Rong YANG Guang-Da AO Feng-Guo LU Jia-Xing |
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| Institution: | Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Deparement, East China Normal University, Shanghai 200062, China |
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| Abstract: | Electrochemical polymerization of aniline and 3‐methylthiophene has been accomplished in 1‐methylimidazium tetrafluoroborate (HMIMBF4) ionic liquid. Homopolymer and copolymers of aniline and 3‐methylthiophene were obtained successfully. The copolymer was studied by cyclic voltammetry and electrochemical impedance spectroscopy. The formation of copolymer has been confirmed by FT‐IR and UV spectra. The atomic force microscope (AFM) was used for microstructural analysis. Both the homopolymer and the copolymer had the catalytic activity for the hydroquinone. |
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| Keywords: | copolymerization aniline 3-methylthiophene ionic liquid hydroquinone |
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