| Synthesis of 15-Demethyl Brefeldin A and Its 7-epi Isomer |
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| 作者姓名： | 沈鑫 杨永青 胡祺 黄嘉慧 高剑 伍贻康 |
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| 作者单位： | State Key Laboratory of Bio-organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （Nos. 20025207, 20272071, 20372075, 20321202, 20672129, 20621062）, and the Chinese Academy of Sciences （Nos. NKGCX2-SW-209, KJCX2.YW.H08）. |
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| 摘 要： | Synthesis of 15-demethyl brefeldin A and its 7-epimer is detailed. X-ray crystallographic structure for 15-demethyl brefeldin A is also disclosed.
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| 关 键 词： | 15-去甲基布雷菲德菌素A 7-差向异构体 抗肿瘤抗菌素 合成 内酯 |
| 修稿时间： | 2006-11-132007-03-10 |
Synthesis of 15-Demethyl Brefeldin A and Its 7-epi Isomer |
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| SHEN, Xin YANG, Yong-Qing HU, Qi HUANG, Jia-Hui GAO, Jian WU, Yi-Kang.Synthesis of 15-Demethyl Brefeldin A and Its 7-epi Isomer[J].Chinese Journal of Chemistry,2007,25(6):802-807. |
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| Authors: | SHEN Xin YANG Yong-Qing HU Qi HUANG Jia-Hui GAO Jian WU Yi-Kang |
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| Institution: | State Key Laboratory of Bio-organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| Abstract: | Synthesis of 15-demethyl brefeldin A and its 7-epimer is detailed. X-ray crystallographic structure for 15-demethyl brefeldin A is also disclosed. |
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| Keywords: | antibiotics asymmetric synthesis analogue lactone |
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