| Synthesis, structure and characterization of the trinuclear copper (Ⅰ) complex [Cu_3(μ_3Br)_2(dppm)_3]Br |
| |
| 引用本文： | 杨瑞娜,孙雨安,胡晓院,金斗满.Synthesis, structure and characterization of the trinuclear copper (Ⅰ) complex [Cu_3(μ_3Br)_2(dppm)_3]Br[J].中国化学,1999(3). |
| |
| 作者姓名： | 杨瑞娜 孙雨安 胡晓院 金斗满 |
| |
| 作者单位： | Henan Institute of Chemistry，Zhengzhou，Henan 450002，China State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing，Jiangsu 210093，China，Zhengzhou Institute of Light Industry，Zhengzhou，Henan 450001，China，Henan Institute of Chemistry，Zhengzhou，Henan 450002，China，Henan Institute of Chemistry，Zhengzhou，Henan 450002，China |
| |
| 基金项目： | Project supported by the National Natural Science Foundation of China (No. 29871009), Nanjing State Key Laboratory of Coordination Chemistry，Natural Science Foundation of Henan Province. |
| |
| 摘 要： | The novel trinuelear copper(I) complex Cu3(μ3-Br)2(dppm)3]Br has been obtained by reaction of bis(diphenyl-phosphino)methane (dppm) with cupric bromide. The title complex was characterized by single-crystal X-ray analysis, elemental analysis, molecular weight determination, 31P NMR and its conductivity was also measured. The Cu3(dppm)3Br2] cation consists of a triangular array of copper atoms, with dppm ligands (Ph2PCH2PPh2) bridging each edge of the triangle and two triply bridging Br groups bound to the two faces of the Cu3 unit. Crystallographic data: monoclinic, space group P21/c, a = 1.4739(4) , b = 1.7708(5), c = 2.8395(8) nm, β= 97.16(3)°, V = 7.353nm3, Z = 4,F(000)= 3296, Dcalc = 1.472 g/cm3, μ= 26.478 cm-1, R = 0.06, Rw = 0.08, 4654 reflections observed with I > 3σ(I).
|
| 本文献已被 CNKI 等数据库收录！ |
|
