| Synthesis,spectra and conductivity of 1-D polymers of nickel(Ⅱ)- and copper(Ⅱ)-porphyrazine with sulfur bridges |
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| 引用本文： | 彭正合,王守兴,杨丽芬,秦子斌.Synthesis,spectra and conductivity of 1-D polymers of nickel(Ⅱ)- and copper(Ⅱ)-porphyrazine with sulfur bridges[J].中国化学,2000(5). |
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| 作者姓名： | 彭正合 王守兴 杨丽芬 秦子斌 |
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| 作者单位： | Department of Chemistry，Wuhan University，Wuhan，Hubei 430072，China，State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing，Jiangsu 210093，China，Department of Chemistry，Wuhan University，Wuhan，Hubei 430072，China，State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing，Jiangsu 210093，China，Department of Chemistry，Wuhan University，Wuhan，Hubei 430072，China，State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing，Jiangsu 210093，China，Department of Chemistry，Wuhan University，Wuhan，Hubei 430072，China，State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing，Jiangsu 210093，China |
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| 基金项目： | Project (No. 29771025) supported by the National Natural Science Foundation of China |
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| 摘 要： | The title polymers PNiPzS4 and PCuPzS4 were synthesized by reaction of phthalonitrile and 2,3,5,6-tetracyano-1,4-dithiin with corresponding metal salt.Their structures and properties were characterized by associating the experimental results with MO and CI calculations of the dinier molecule as model polymer in the ZJNDO method.It has been found that the PNiPzS4 (or PCuPzS4) shows the semiconductivity at T<253 K (or 260 K) and T>278 K (or 286 K) and the conductivity increase with a hoist of temperature at 253 K (or 260 K)
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