| A novel pentaazadentate bismacrocyclic cadmium complex |
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| 作者姓名： | 郭丰启 董世明 王夺元 |
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| 作者单位： | Laboratory of Photochemistry，Center of Molecule Science，Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080，China，Laboratory of Photochemistry，Center of Molecule Science，Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080，China，Laboratory of Photochemistry，Center of Molecule Science，Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080，China |
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| 基金项目： | Project (No. 29832030, 2982001) supported by the National Natural Science Foundation of China. |
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| 摘 要： | A novel pentaazadentate bismacrocyde was synthesized through an improved procedure of 1:1 Schiff base condensation of diformyltripyrrane with 3, 4, 3', 4'-tetraamino-biphenyl hydrochloride using Ph2 as template ion, in which the condensed byproduct water was removed efficiently to make the yield over 90%. Then the bismacrocyclic ligand reacted with cadmium chloride to yield the title metal complex with molecular weight being 1200.4 by TOF MS and the λmax being 766 nm.
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A novel pentaazadentate bismacrocyclic cadmium complex |
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| GUO,Feng-Qi DONG,Shi-Ming WANG,Duo-YuanLaboratory of Photochemistry,Center of Molecule Science.A novel pentaazadentate bismacrocyclic cadmium complex[J].Chinese Journal of Chemistry,2000(4). |
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| Authors: | GUO Feng-Qi DONG Shi-Ming WANG Duo-YuanLaboratory of Photochemistry Center of Molecule Science |
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| Institution: | GUO,Feng-Qi DONG,Shi-Ming WANG,Duo-YuanLaboratory of Photochemistry,Center of Molecule Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China |
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| Abstract: | |
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| Keywords: | Pentaazadentate bismacrocyclic cadmium complex isotopes absorbance |
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