| 以不同的环内酰胺为手性辅助剂的烯酰基环内酰胺的立体选择环氧化反应 |
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| 引用本文： | 张殊佳,陈永康,李慧明,黄维扬,Rogatchov Viktor,Metz Peter.以不同的环内酰胺为手性辅助剂的烯酰基环内酰胺的立体选择环氧化反应[J].中国化学,2006,24(5):681-688. |
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| 作者姓名： | 张殊佳 陈永康 李慧明 黄维扬 Rogatchov Viktor Metz Peter |
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| 作者单位： | [1]College of Environment and Chemical Engineering, Dalian University, Dalian, Liaoning 116622, China [2]Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China [3]Institut für Organische Chemie, Technische Universitat Dresden, D-01069, Dresden, Germany |
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| 摘 要： | Asymmetric epoxidation of N-enoylsultams （1, 3-15） incorporating a variety of chiral sultams as the chiral induction elements with UHP/TFAA has been studied. Both diastereomeric isomers of epoxides （2, 16-28） were obtained in high yield and moderate to high optical purity.
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| 关 键 词： | 不对称环氧化作用 手性助剂 N-烯酰磺内酰胺 合成 手性碘内酰胺 |
| 收稿时间： | 2005-06-30 |
| 修稿时间： | 2005-06-302006-01-24 |
Diastereoselective Epoxidation of N-Enoylsultams with Different Chiral Sultams as Auxiliaries |
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| ZHANG, Shu-Jia CHEN, Yong-Kang LI, Hui-Ming HUANG, Wei-Yang.Diastereoselective Epoxidation of N-Enoylsultams with Different Chiral Sultams as Auxiliaries[J].Chinese Journal of Chemistry,2006,24(5):681-688. |
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| Authors: | ZHANG Shu-Jia CHEN Yong-Kang LI Hui-Ming HUANG Wei-Yang |
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| Abstract: | Asymmetric epoxidation of N‐enoylsultams ( 1 , 3–15 ) incorporating a variety of chiral sultams as the chiral induction elements with UHP/TFAA has been studied. Both diastereomeric isomers of epoxides ( 2 , 16–28 ) were obtained in high yield and moderate to high optical purity. |
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| Keywords: | asymmetric epoxidation chiral auxiliary enoylsultam synthesis |
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