| A Novel Octahedral Hexasilver(I) Cluster: Ag_6[SSCN(n-C_4H_9)_2]_6 |
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| 作者姓名： | 章伟光 钟昀 谭民裕 刘伟生 苏成勇 |
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| 作者单位： | ZHANG，Wei Guang ZHONG，Yun TAN，Min YuLIU，Wei Sheng SU，Cheng Yong aDepartment of Chemistry，Lanzhou University，Lanzhou，Gansu 730000，China bDepartment of Chemistry，South China Normal University，Guangzhou，Guangdong 510631，Ch |
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| 基金项目： | ProjectsupportedbytheNaturalScienceFoundationofGuangdongProvince (No .990 4 63)andtheNationalNaturalScienceFounda tionofChina (No .2 95 6 10 0 2 ) |
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| 摘 要： | ＣｏｍｐｏｕｎｄｓｆｏｒｍｅｄｆｒｏｍＣｕ ,ＡｇａｎｄＡｕｗｉｔｈｄｉｔｈｉｏ ｌａｔｅｌｉｇａｎｄｓ ,ｓｕｃｈａｓｔｈｅｄｉａｌｋｙｌｄｉｔｈｉｏｃａｒｂａｍａｔｅ (ＤＴＣ) ,ｍｅｒｃａｐｔｏｔｈｉａｚｏｌｉｎｅ (ＨＭＴ)ａｎｄｄｉａｌｋｙｌｄｉｔｈｉｏｐｈｏｓｐｈａｔｅｓ(ＤＤＰ) ,ｈａｖｅｐｌａｙｅｄａｎｉｍｐｏｒｔａｎｔｒｏｌｅｉｎｔｅｃｈｎｏｌｏｇｙ .1Ｃｕ(Ｉ) Ｓｃｌｕｓｔｅｒｓａｌｓｏｈａｖｅｂｅｅｎｉｍｐｌｉｃａｔｅｄｉｎｂｉｏｌｏｇｙａｓａｎ ｔｉ ｏｘｉｄａｎｔｓ .2Ｔｈｅｃｕｂａｎ…
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A Novel Octahedral Hexasilver(I) Cluster: Ag_6[SSCN(n-C_4H_9)_2]_6 |
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| ZHANG,Wei Guang ZHONG,Yun TAN,Min YuLIU,Wei Sheng SU,Cheng Yong a.A Novel Octahedral Hexasilver(I) Cluster: Ag_6[SSCN(n-C_4H_9)_2]_6[J].Chinese Journal of Chemistry,2002(5). |
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| Authors: | ZHANG Wei Guang ZHONG Yun TAN Min YuLIU Wei Sheng SU Cheng Yong a |
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| Institution: | ZHANG,Wei Guang ZHONG,Yun TAN,Min YuLIU,Wei Sheng SU,Cheng Yong aDepartment of Chemistry,Lanzhou University,Lanzhou,Gansu 730000,China bDepartment of Chemistry,South China Normal University,Guangzhou,Guangdong 510631,Ch |
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| Abstract: | The first crystal structural report of a AgDTC complex (DTC= dialkyldithiocarbamate, R= n butyl) presented in this paper shows that it is a hexanuclear species. The structural arrangement for the DDP (dialkyldithiophosphate) ligands is different from that of Cu 6(DDP) 6, but is the same as that of Ag 6 SSP(O i Pr) 2] 6. |
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| Keywords: | X ray crystal structure cluster silver n dibutyldithiocarbamate complex |
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