| Ship-in-bottle formation of Ru_3(CO)_(12) in NaY zeolite |
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| 作者姓名： | XIAO Feng-Shou XU Ru-Ren HE Ya-Nan |
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| 作者单位： | XIAO，Feng-Shou XU，Ru-Ren HE，Ya-Nan Department of Chemistry，Jilin University，Changchun，Jilin 130023，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China for Young Scientists and the Excellent Junior Faculty Foundation of the State Education Commission. |
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| 摘 要： | NaY zeolite entrapped Ru3(CO)12 cluster has been synthesized from RuCl3 ion-exchanged NaY, which is well characterized by IR and Raman spectroscopies and CO chemisorp-tion. When the Ru3+/NaY sample is heated from 298 K to 393 K for 25 h and for 10 h at 393 K, the sample colour changes from dark to brown-yellow. The in situ infrared spectrum exhibits absorption bands at 2130, 2064, 2040, 2017, 1990, 1953 and 1925 cm-1. The bands at 2130 cm-1 arises from the Runm+(CO)l m =1-3;n = 1 - 3; l = 1-12). The bands at 2064, 2040, 2017 and 1990 cm-1 are proposed to be associated with the Ru3(CO)12/NaY, which are close to Ru3(CO)12 crystalline. Furthermore, the Raman results provide bands at 150 and 185 cm-1, which can be attributed to Ru-Ru bonds of the sample as in the case of Ru3(CO)12 crystalline, for which the A1' Ru-Ru stretching mode is assigned to 185 cm-1 and E1' Ru-Ru stretching mode is assigned to a band at 150 cm-1, respectively. CO chemisorption of Ru3]/NaY gives a CO/Ru ratio of 3.85, which is simila
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Ship-in-bottle formation of Ru_3(CO)_(12) in NaY zeolite |
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| XIAO,Feng-Shou XU,Ru-Ren HE,Ya-Nan.Ship-in-bottle formation of Ru_3(CO)_(12) in NaY zeolite[J].Chinese Journal of Chemistry,1994,12(3):258-264. |
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| Authors: | XIAO Feng-Shou XU Ru-Ren HE Ya-Nan |
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| Institution: | XIAO,Feng-Shou XU,Ru-Ren HE,Ya-Nan Department of Chemistry,Jilin University,Changchun,Jilin 130023,China |
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| Abstract: | NaY zeolite entrapped Ru3(CO)12 cluster has been synthesized from RuCl3 ion-exchanged NaY, which is well characterized by IR and Raman spectroscopies and CO chemisorp-tion. When the Ru3+/NaY sample is heated from 298 K to 393 K for 25 h and for 10 h at 393 K, the sample colour changes from dark to brown-yellow. The in situ infrared spectrum exhibits absorption bands at 2130, 2064, 2040, 2017, 1990, 1953 and 1925 cm-1. The bands at 2130 cm-1 arises from the Runm+(CO)l m =1-3;n = 1 - 3; l = 1-12). The bands at 2064, 2040, 2017 and 1990 cm-1 are proposed to be associated with the Ru3(CO)12/NaY, which are close to Ru3(CO)12 crystalline. Furthermore, the Raman results provide bands at 150 and 185 cm-1, which can be attributed to Ru-Ru bonds of the sample as in the case of Ru3(CO)12 crystalline, for which the A1' Ru-Ru stretching mode is assigned to 185 cm-1 and E1' Ru-Ru stretching mode is assigned to a band at 150 cm-1, respectively. CO chemisorption of Ru3]/NaY gives a CO/Ru ratio of 3.85, which is similar to the stoichiometry of Ru3(CO)12. |
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| Keywords: | Cluster ruthenium carbonyl NaY zeolite infrared Raman CO chemisorption |
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