| Standard Gibbs energies of transfer of rubidium tetraphenylborate from water to straight-chain n-alkanols |
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| 作者姓名： | 邹立壮 王晓玲 王风阁 张丕俭 郭相坤 周保学 屈松生 |
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| 作者单位： | Department of Chemistry，Yantai Teacher's College，Yantai，Shandong 264025，China，Department of Chemistry，Yantai Teacher's College，Yantai，Shandong 264025，China，Department of Chemistry，Yantai Teacher's College，Yantai，Shandong 264025，China，Department of Chemistry，Yantai Teacher's College，Yantai，Shandong 264025，China，Department of Chemistry，Yantai Teacher's College，Yantai，Shandong 264025，China，Department of Chemistry，Shandong Normal University，Jinan，Shandong 250014，China，Department of Chemistry，Wuhan University，Wuhan，Hubei 430072，China |
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| 摘 要： | Solubilities of ribidium tetraphenylborate in water,methanol,ethanol,1-propanol,1-butanol,l-pentanol,1-hexanol and 1-octanol at 288.15,298.15,308.15,318.15,328.15 K have been determined by spectrophotometry.The standard Gibbs energy of transfer of ribidium tetraphenylborate from water to straight-chain n-alkanols and the primary medium effect of rubidium tetraphenylborate from 288.15 to 328.15 K have been calculated.Furthermore,the contribution of microscopic interactions to the standard Gibbs energy of transfer of rubidium tetraphenylborate is calculated and discussed.
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Standard Gibbs energies of transfer of rubidium tetraphenylborate from water to straight-chain n-alkanols |
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| ZOU,Li-ZhuangWANG,Xiao-Ling WANG,Feng-Ge ZHANG,Pi-JianGUO,Xiang-Kun ZHOU,Bao-Xue QU,Song-Sheng.Standard Gibbs energies of transfer of rubidium tetraphenylborate from water to straight-chain n-alkanols[J].Chinese Journal of Chemistry,1998,16(4):303-310. |
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| Authors: | ZOU Li-ZhuangWANG Xiao-Ling WANG Feng-Ge ZHANG Pi-JianGUO Xiang-Kun ZHOU Bao-Xue QU Song-Sheng |
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| Institution: | ZOU,Li-ZhuangWANG,Xiao-Ling WANG,Feng-Ge ZHANG,Pi-JianGUO,Xiang-Kun ZHOU,Bao-Xue QU,Song-ShengDepartment of Chemistry,Yantai Teacher's College,Yantai,Shandong 264025,ChinaDepartment of Chemistry,Shandong Normal University,Jinan,Shandong 250014,ChinaDepartment of Chemistry,Wuhan University,Wuhan,Hubei 430072,China |
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| Abstract: | Solubilities of ribidium tetraphenylborate in water,methanol,ethanol,1-propanol,1-butanol,l-pentanol,1-hexanol and 1-octanol at 288.15,298.15,308.15,318.15,328.15 K have been determined by spectrophotometry.The standard Gibbs energy of transfer of ribidium tetraphenylborate from water to straight-chain n-alkanols and the primary medium effect of rubidium tetraphenylborate from 288.15 to 328.15 K have been calculated.Furthermore,the contribution of microscopic interactions to the standard Gibbs energy of transfer of rubidium tetraphenylborate is calculated and discussed. |
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| Keywords: | Rubidium tetraphenylborate solubility standard Gibbs energy of transfer primary medium effect |
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