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Na2S2O4-Mediated Cyclocondensations of 2,2'-Disulfanediyldianilines with Aldehydes: A Facile and Inexpensive Method for the Synthesis of 2-Substituted Benzothiazoles
Authors:Wang Zhanglin  Tang Riyuan  Li Jinheng
Institution:College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, China
Abstract:A facile and inexpensive method for the synthesis of 2‐substituted benzothiazoles has been developed by Na2S2O4‐mediated cyclocondensations of 2,2′‐disulfanediyldianilines with aldehydes. In the presence of Na2S2O4 and 4 Å molecular sieves, a variety of 2‐substituted benzothiazoles were obtained from the reaction of 2,2′‐disulfanediyldianilines with aldehydes in moderate to high yields.
Keywords:Na2S2O4  cyclocondensation  2  2′‐disulfanediyldianiline  aldehyde  benzothiazole
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