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Synthesis of N-(4-Salicylideneiminoaryl)monoaza Crown Ethers and Dioxygen Affinities of Their Cobalt(II) Complexes
作者姓名:曾伟  李鸿波  向瑞礼  魏星耀  秦圣英
作者单位:Department of Chemistry,Sichuan University,Chengdu,Sichuan 610064,China,Department of Chemistry,Sichuan University,Chengdu,Sichuan 610064,China,Analytical and Testing Center,Sichuan University,Chengdu,Sichuan 610064,China,Department of Chemistry,Sichuan University,Chengdu,Sichuan 610064,China,Department of Chemistry,Sichuan University,Chengdu,Sichuan 610064,China
基金项目:ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 95 72 0 5 9)
摘    要:IntroductionSchiffbasesandtheirmetalcomplexeshavebeenap pliedwidelyinthefieldofcatalyticchemistry ,liquidcrystalsandphotochromism .1 3ManySchiffbaseligandscontainingcrownetherpossessdifferentrecognitionsitesforbothalkaliandtransitionmetalguestcations,4 forexample ,theNa(I)orK(I) /Co(II)hetero nuclearcomplexesofcrownedSchiffbasecanbindoxygenmolecule (O2 )toformstablesoliddioxygenadducts .5 7Gebbinkandco workershavereportedaK(I) /Cu(II)sandwichcomplexwhichcanacceleratethefor mationofdioxyg…


Synthesis of N-(4-Salicylideneiminoaryl)monoaza Crown Ethers and Dioxygen Affinities of Their Cobalt(II) Complexes
Abstract:
Keywords:synthesis  monoaza crown ether  cobalt(II)  Schiff base complex  oxygenation
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