Synthesis of N-(4-Salicylideneiminoaryl)monoaza Crown Ethers and Dioxygen Affinities of Their Cobalt(II) Complexes |
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作者姓名: | 曾伟 李鸿波 向瑞礼 魏星耀 秦圣英 |
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作者单位: | Department of Chemistry,Sichuan University,Chengdu,Sichuan 610064,China,Department of Chemistry,Sichuan University,Chengdu,Sichuan 610064,China,Analytical and Testing Center,Sichuan University,Chengdu,Sichuan 610064,China,Department of Chemistry,Sichuan University,Chengdu,Sichuan 610064,China,Department of Chemistry,Sichuan University,Chengdu,Sichuan 610064,China |
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基金项目: | ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 95 72 0 5 9) |
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摘 要: | IntroductionSchiffbasesandtheirmetalcomplexeshavebeenap pliedwidelyinthefieldofcatalyticchemistry ,liquidcrystalsandphotochromism .1 3ManySchiffbaseligandscontainingcrownetherpossessdifferentrecognitionsitesforbothalkaliandtransitionmetalguestcations,4 forexample ,theNa(I)orK(I) /Co(II)hetero nuclearcomplexesofcrownedSchiffbasecanbindoxygenmolecule (O2 )toformstablesoliddioxygenadducts .5 7Gebbinkandco workershavereportedaK(I) /Cu(II)sandwichcomplexwhichcanacceleratethefor mationofdioxyg…
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Synthesis of N-(4-Salicylideneiminoaryl)monoaza Crown Ethers and Dioxygen Affinities of Their Cobalt(II) Complexes |
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Abstract: | |
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Keywords: | synthesis monoaza crown ether cobalt(II) Schiff base complex oxygenation |
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