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二价铜离子和联咪唑催化的酚与碘代芳烃的乌尔曼反应研究
引用本文:王保安,曾润生,韦慧勤,贾爱铨,邹建平.二价铜离子和联咪唑催化的酚与碘代芳烃的乌尔曼反应研究[J].中国化学,2006,24(8):1062-1065.
作者姓名:王保安  曾润生  韦慧勤  贾爱铨  邹建平
作者单位:[1]Departtnent of Chemistry Jiaozuo Normal College, Jiaozuo, Henan 454150, China [2]Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University. Suzhou, Jiangsu 215123, China
基金项目:Project supported by the Taicang Puyuan Chemical Co., Ltd. The authors like to thank good suggestions from MA, Da-Wei of Shanghai Institute of 0rganic Chemistry, Chinese Academy of Sciences, China.
摘    要:Ullmann-type diaryl ether synthesis can be performed at 100 ℃ in good to excellent yields by aryl iodides as the substrates under the assistance of copper(Ⅱ) and 2,2'-biimidazolyl.

关 键 词:铜(Ⅱ)  催化反应  Ullmann耦合反应  2  2'-二亚胺偶氮基  二芳基醚  苯酚  芳基碘化物
收稿时间:2005-11-01
修稿时间:2005-11-012006-04-21

Copper(II) and 2,2′‐Biimidazolyl‐promoted Ullmann Coupling Reaction of Phenols and Aryl Iodides
WANG Bao-An, ZENG Run-Sheng, WEI Hui-Qin, JIA Ai-Quan, ZOU Jian-Ping.Copper(II) and 2,2′‐Biimidazolyl‐promoted Ullmann Coupling Reaction of Phenols and Aryl Iodides[J].Chinese Journal of Chemistry,2006,24(8):1062-1065.
Authors:WANG Bao-An  ZENG Run-Sheng  WEI Hui-Qin  JIA Ai-Quan  ZOU Jian-Ping
Institution:Department of Chemistry, Jiaozuo Normal College, Jiaozuo, Henan 454150, China; Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, and Chemical Engineering, Suzhou University. Suzhou, Jiangsu 215123, China
Abstract:Ullmann‐type diaryl ether synthesis can be performed at 100 °C in good to excellent yields by aryl iodides as the substrates under the assistance of copper(II) and 2,2′‐biimidazolyl.
Keywords:Copper(II)‐catalyzed Ullmann reaction  2  2′‐biimidazolyl  diaryl ether
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