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XANES at Eu-L3 edge and valence of europium in SrB_4O_7: Eu and BaB_8O_(13): Eu
作者姓名:梁宏斌  胡天斗  王淑彬  曾庆华  裴治武  苏锵
作者单位:Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,Jilin 130022,China,Laboratory of Synchrontron Radiation,Institute of High Energy Physics,Chinese Academy of Sciences,Beijing,100039,China,Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,Jilin 130022,China,Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,Jilin 130022,China,Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,Jilin 130022,China,Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,Jilin 130022,China
基金项目:Project supported by the State Key Project of Basic Research (Project 973) (No. G1998061312), the National Natural Science Foundation of China (No. 29771029) and the Foundation of Laboratory of Beijing Synchrontron Radiation, Institute of High Energy Phy
摘    要:The luminescent materials SrB4O7: Eu and BaB8O13: Eu were synthesized, and the valence states of europium in the materials were measured by means of XANES at Eu-L3 edge. It is found that the Eu3 and Eu2 ions are all present in the materials, and more Eu3 ions can be reduced in SrB4O7: Eu than in BaB8O13:Eu. The excitation and emission spectra of Eu3 in SrB4O7: Eu and BaB8O13:Eu were determined.


XANES at Eu-L3 edge and valence of europium in SrB_4O_7: Eu and BaB_8O_(13): Eu
LIANG,Hong-Bin HU,Tian-Dou WANG,Shu-BinZENG,Qing-Hua PEI,Zhi-Wu SU,Qiang Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,Jilin ,China Laboratory of Synchrontron Radiation.XANES at Eu-L3 edge and valence of europium in SrB_4O_7: Eu and BaB_8O_(13): Eu[J].Chinese Journal of Chemistry,2000,18(3):294-296.
Authors:LIANG  Hong-Bin HU  Tian-Dou WANG  Shu-BinZENG  Qing-Hua PEI  Zhi-Wu SU  Qiang Laboratory of Rare Earth Chemistry and Physics  Changchun Institute of Applied Chemistry  Chinese Academy of Sciences  Changchun  Jilin  China Laboratory of Synchrontron Radiation
Institution:LIANG,Hong-Bin HU,Tian-Dou WANG,Shu-BinZENG,Qing-Hua PEI,Zhi-Wu SU,Qiang Laboratory of Rare Earth Chemistry and Physics,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun,Jilin 130022,China Laboratory of Synchrontron Radiation,Institute of High Energy Physics,Chinese Academy of Sciences,Beijing,100039,China
Abstract:The luminescent materials SrB4O7: Eu and BaB8O13: Eu were synthesized, and the valence states of europium in the materials were measured by means of XANES at Eu-L3 edge. It is found that the Eu3 and Eu2 ions are all present in the materials, and more Eu3 ions can be reduced in SrB4O7: Eu than in BaB8O13:Eu. The excitation and emission spectra of Eu3 in SrB4O7: Eu and BaB8O13:Eu were determined.
Keywords:Strontium tetraborate  barium octaborate  europium  valence state  XANES  luminescence
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