A new strategy for the synthesis of unsymmetrical phosphotriesters |
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| Authors: | HU Jun DING Yi-Xiang |
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| Institution: | HU,Jun DING,Yi-XiangShanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China |
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| Abstract: | A new strategy for the synthesis of unsymmetrical phosphotri-esters was reported: an alcohol was converted to unsymmetrical dialkyl phosphites firstly, which then reacted with the second alcohol or phenol to afford required unsymmitrical triesters in the presence of iodine in high yields under exceptionally mild conditions. |
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| Keywords: | Unsymmetrical phosphotriesters dialkyl phosphites phosphorylation |
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