| 基于1,6-己二醇的哑铃型树状大分子 |
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| 引用本文： | 唐新德,张其震,李爱香,范星河,陈小芳,周其凤.基于1,6-己二醇的哑铃型树状大分子[J].中国化学,2005,23(1):11-13. |
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| 作者姓名： | 唐新德 张其震 李爱香 范星河 陈小芳 周其凤 |
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| 作者单位： | [1]CollegeofChemistryandMolecularEngineering,PekingUniversity,Beijing100871,China [2]SchoolofChemistryandChemicalEngineering,ShandongUniversity,Jinan,Shandong250100,China／／SchoolofChemistryandChemicalEngineering,JinanUniversity,Jinan,Shandong250022,China [3]SchoolofChemistryandChemicalEngineering,ShandongUniversity,Jinan,Shandong250100,China |
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| 摘 要： | Novel carbosilane dendrimers based on 1,6-hexanediol were prepared by divergent approach. Using 1,6-hexanediol-based diallyl ether as the core molecule, the dendrimers were prepared to the third generation with 54 allyl groups on the periphery by alternate hydrosilylation-allylation reactions.
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| 关 键 词： | 合成 枝状碳硅烷 1 6-己二醇 二苯基醚 氢化硅烷化 烯丙基化 |
| 收稿时间： | 2004-4-27 |
| 修稿时间： | 2004-10-26 |
Dumbbell‐shaped Carbosilane Dendrimers Based on 1,6‐Hexanediol |
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| Xin‐De Tang,Qi‐Zhen Zhang,Ai‐Xiang Li,Xing‐He Fan,Xiao‐Fang Chen,Qi‐Feng Zhou.Dumbbell‐shaped Carbosilane Dendrimers Based on 1,6‐Hexanediol[J].Chinese Journal of Chemistry,2005,23(1):11-13. |
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| Authors: | Xin‐De Tang Qi‐Zhen Zhang Ai‐Xiang Li Xing‐He Fan Xiao‐Fang Chen Qi‐Feng Zhou |
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| Abstract: | Novel carbosilane dendrimers based on 1,6‐hexanediol were prepared by divergent approach. Using 1,6‐hexanediol‐based diallyl ether as the core molecule, the dendrimers were prepared to the third generation with 54 allyl groups on the periphery by alternate hydrosilylation‐allylation reactions. |
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| Keywords: | 1 6‐hexanediol carbosilane dendrimer hydrosilylation allylation |
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