| Catalytic Asymmetric[2,3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Carbenoids and Allenic 2-Methylphenyl Sulfide |
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| 引用本文： | 张晓梅,马明,王剑波. Catalytic Asymmetric[2,3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Carbenoids and Allenic 2-Methylphenyl Sulfide[J]. 中国化学, 2003, 0(7) |
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| 作者姓名： | 张晓梅 马明 王剑波 |
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| 作者单位： | Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education，Department of Chemical Biolegy，College of Chemistry，Peking University，Beijing 100871，China，Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education，Department of Chemical Biolegy，College of Chemistry，Peking University，Beijing 100871，China，Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education，Department of Chemical Biology，College of Chemistry，Peking University，Beijing 100871，China State Key Laboratory of Elemento-Organic Chemistry，Nankai University，Tianjin 300071，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China(Nos.20225205 and 20172002),State Key Laboratory of Elemento-Organic Chemistry of Nankai University and by Trans-Century Training Programme foundation for the Talents by Ministry of Edu |
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| 摘 要： | The first investigation on catalytic asymmetric [2, 3]-sigmatrop-ic rearrangement of sulfur ylides generated from carbenoids andallenic phenyl sulfide was carried out. Up to 55% ee value wasobtained.
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Catalytic Asymmetric [2, 3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Carbenoids and Allenic 2-Methylphenyl Sulfide |
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| ZHANG,Xiao-Mei MA,Ming WANG,Jian-Bo Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education. Catalytic Asymmetric [2, 3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Carbenoids and Allenic 2-Methylphenyl Sulfide[J]. Chinese Journal of Chemistry, 2003, 0(7) |
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| Authors: | ZHANG Xiao-Mei MA Ming WANG Jian-Bo Key Laboratory of Bioorganic Chemistry Molecular Engineering of Ministry of Education |
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| Affiliation: | ZHANG,Xiao-Mei MA,Ming WANG,Jian-Bo Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,Department of Chemical Biology,College of Chemistry,Peking University,Beijing 100871,China State Key Laboratory of Elemento- Organic Chemistry,Nankai University,Tianjin 300071,China |
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| Abstract: | The first investigation on catalytic asymmetric [2,3]-sigmatrop-ic rearrangement of sulfur ylides generated from carbenoids and allenic phenyl sulfide was carried out. Up to 55% ee value was obtained. |
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| Keywords: | carbenoid sulfur ylide [2 3 ]-sigmatropic rear-rangement catalytic asymmetric synthesis |
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