Enhancement of tensile,electrical and thermal properties of epoxy nanocomposites through chemical hybridization of polypyrrole and graphene oxide |
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| Institution: | 1. Center for Advanced Materials, Qatar University, PO Box 2713, Doha, Qatar;2. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovského nám. 2, 162 06 Praha, Czechia;1. Institute of Fundamental Technological Research, PAS, Warsaw, Poland;2. Institute of Materials Science, University of Silesia, Katowice, Poland;3. Aichi Institute of Technology, Toyota-city, Japan;4. SMP Technologies Inc., Tokyo, Japan;1. Department of Mechanical Engineering, Faculty of Engineering of Bilbao, University of the Basque Country (UPV/EHU), Rafael Moreno “Pitxitxi” 2-3, 48013 Bilbao, Spain;2. Department of Mining, Metallurgy and Science of Materials, Faculty of Engineering of Bilbao, University of the Basque Country (UPV/EHU), Rafael Moreno “Pitxitxi” 2-3, 48013 Bilbao, Spain;3. Materials Testing and Simulation, Leartiker (Lea-Artibai Development Center), Xemein Avenue 12-A, 48270 Markina, Xemein, Spain;1. Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang, 621900, China;2. College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, 610065, China |
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| Abstract: | This paper presents the properties of epoxy nanocomposites, prepared using a synthesized hybrid Polypyrrole-Graphene Oxide (PPy-GO) filler, via in-situ chemical polymerization, at various filler loadings (i.e., 0.5–2 w. t %). The microstructures and properties of the PPy-GO hybrids and epoxy nanocomposites were studied via Fourier transform infrared (FTIR), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), mechanical (Tensile Properties), electrical, Dynamic mechanical thermal analysis (DMTA) and thermogravimetric analyses (TGA). Morphological study demonstrated that varying the nanofiller nature (PPy-GOs, PPy or GO) lead to different states of dispersion. Mechanical, electrical and thermal analysis demonstrated that the hybrid concentration and its architecture (PPy:GO ratio) are interesting factors significantly affected the properties of the epoxy based nanocomposites. On the other hand, the mechanical performance of the cured nanocomposites outperformed the PPy-GO, with enhancements of 78% and 51% of Young's modulus and strength, respectively. Here it has been established that the embedding of PPy-GO hybrids into pristine epoxy endows optimum dispersion of PPy and GO as well as better interfacial adhesion between the fillers and matrix, which results in a significant improvement in load transfer effectiveness. Electrical conductivity measurements showed that conductivity of epoxy filled nanocomposites increased up 10−4 S/cm for Epoxy/PPy-GO nanocomposites. DMTA test indicated that incorporation of PPy-GO resulted in a significantly increase in Tg of the resultant nanocomposites, which is attributed to the highly exfoliation structure and the stronger interfacial interaction. The PPy-GO particles enhanced electrical, thermal and mechanical properties of nanocomposites, confirming the synergistic effect of PPy-GO as multifunctional filler. |
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| Keywords: | PPy-GO hybrids Nanocomposite Synergistic effect Mechanical properties |
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