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Superhydrophobic and superoleophilic polyethylene aerogel coated natural rubber latex foam for oil-water separation application
Institution:1. College of Mechanical and Automotive, South China University of Technology, Guangzhou 510640, China;2. Guangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced Manufacturing, South China University of Technology, Guangzhou 510640, China;3. Key laboratory of Processing and Quality Evaluation Technology of Green Plastics of China National Light Industry council, Beijing Technology and Business University, Beijing 100048, China;4. SCNU Qingyuan Institute of Science and Technology Innovation Co., Ltd., Qingyuan 511517, China;1. Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094, China;2. Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology, Nanjing Institute of Technology, Nanjing 211167, China;3. Department of Chemistry, Xi''an Jiaotong-Liverpool University, Suzhou 215123, China;4. Key Laboratory of C & PC Structures of Ministry of Education, Southeast University, Nanjing 210096, China
Abstract:The oil-water separation has made an attention due to over-increased production of oily water from the industrial process and everyday routine of humans. The current work reports on preparation and characterization of High-Density Polyethylene (HDPE) aerogel coated Natural Rubber Latex foam (NRLF) with superhydrophobic and superoleophilic character, good sorption capacity for oil-water separation application and were investigated. The HDPE aerogel and the coated NRLF material was prepared by a cooling process from a solution of HDPE in xylene solvent (HDPE sole, which resulted into thermally induced phase separation of the Polyethylene molecular network). The HDPE aerogel coated NRLF displayed a porous surface morphology with particle-like structural features. The HDPE aerogel coated NRLF showed superhydrophobicity with static water contact angle >150°. The effect and recyclability of the HDPE aerogel coated NRLF for oil-water separation was investigated using different model oil solvents to explore their repeatable application in oil spill clean-up process. Modified NRLF shows an excellent mechanical property (compressibility). The average modulus and average stiffness of the modified NRLF increased with the increase of the concentration of HDPE sol. The modified superhydrophobic sponge has good durability under acid and base conditions.
Keywords:Superhydrophobic & superoleophilic foam  Polyehtylene aerogel  Oil-water separation
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