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Synthesis and Properties of Highly Photoluminescent and Electrochemically Active Polymers Containing 2‐Pyrazoline Units in the Main Chain
Authors:Qiang Fang  Biao Jiang  Bing Xu  Amin Cao
Abstract:Summary: Two new polymers containing 2‐pyrazoline units in the main chain were synthesized for the first time by a Suzuki polycondensation between a 2‐pyrazoline monomer and aryl diboronic esters. The polymers showed high photoluminescence (PL) in both the solution and the solid state; quantum yields of PL in toluene were higher than 76%. Thermogravimetric analysis and cyclic voltammetry showed that the polymers had high thermal stability and good reversibility under electrochemical oxidation.

New polymers ( 2 and 3 ) with strong photoluminescence and good reversibility under electrochemical oxidation were synthesized here.

Keywords:electrochemical properties  optical properties  photoluminescent polymer  polycondensation  pyrazoline derivatives
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