Electrochemical fluorination of N,N-dimethylperfluoroacylamides |
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| Authors: | Nikolai V Ignat’ev Michael SchmidtUdo Heider Andriy KucherinaPeter Sartori Fatiah M Helmy |
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| Institution: | a Merck KGaA, Frankfurter Str. 250, D-64271 Darmstadt, Germany
b Institut für Synthesechemie, Gerhard-Mercator-University of Duisburg, Lotharstrasse 1, D-47048 Duisburg, Germany |
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| Abstract: | The electrochemical fluorination (ECF) of N,N-dimethylperfluoroacylamides gives the corresponding perfluoro-N,N-dimethylacylamides in low yield. With increase of the number of carbon atoms in the perfluoroacyl radical the yield of the required perfluoro-N,N-dimethylacylamides is slightly increased. |
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| Keywords: | Electrochemical fluorination Simons process N N-dimethylperfluoroacylamides Perfluoro-N N-dimethylacylamides |
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