1. Institute of Surface Chemistry, N.A.S. of Ukraine , Kyiv , 252026 , Ukraine;2. Dept. of Physics , Kyoto University , Kitashirakawa, Sakyoku, Kyoto , 606-8502 , Japan
Abstract:
Abstract First order phase transition at 163–172 K is found in the (BEDT-TTF)3AgxI8 compound in close vicinity to the temperature range of superionic conductivity. This observation indicates formation of the mobile silver ions in the salt as a consequence of sublattice melting.