Synthesis and crystal structure of a novel polymeric silver(I) complex |
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| Authors: | Tao Zheng Ai–Jing Sun Yan–Hong Guo De–Yan Bu Zhi–Rong Qu |
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| Institution: | 1. College of Chemistry and Chemical Engineering, Southeast University, Nanjing, P. R. China;2. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hang zhou Normal University, Hang zhou, P. R. China |
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| Abstract: | The complex of Ag2(μ–L)2(μ–NO3)2]n, where L?=?2–methyl–5–(2–pyridyl)–1,3,4–oxadiazole, has been synthesized and characterized by single–crystal X–ray diffraction analysis. The crystals are in triclinic system with space group P–1. Complex Ag2(μ–L)2(μ–NO3)2]n is a polymeric silver(I) complex bridged through the 1,3,4–oxadiazole rings and the nitrate ions, and the center Ag1(I) atoms have distorted trigonal bipyramidal geometries AgN3O2]. |
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| Keywords: | Crystal structure synthesis silver(I) complex 1 3 4–oxadiazole |
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