Two new CrIII(bpb)(H2O)X complexes derived from [Cr(bpb)(N3)2]− or [Cr(bpb)(CN)2]− (bpb2− = 1,2-bis(pyridine-2-carboxamido)benzenate, X− = hydroxo or azide) |
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Authors: | Zhong-Hai Ni Hui-Zhong Kou Li-Fang Zhang Chunhua Ge Ru-Ji Wang Ai-Li Cui |
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Institution: | (1) Department of Chemistry, Tsinghua University, Beijing, 100084, China |
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Abstract: | Two new Cr(III) complexes, Cr(bpb)(H2O)(OH)]·3H2O (1) and Cr(bpb)(H2O)(N3)]·H2O (2) have been synthesized and structurally characterized. Both complexes were unexpectedly obtained as single crystals during the reactions of Cr(bpb)(CN)2]− or Cr(bpb)(N3)2]− with Ni(L)](ClO4)2 (L = 3,10-dimethyl-1,3,6,8,10,12-hexaazacyclotetradecane) or MX2·nH2O (M = Cu, Ni and Mn, X = Cl− and ClO4
−). Complex 1 crystallizes in the triclinic system, space group P-1, formula CrC18H21N4O7 with a = 7.1543(17) ?, b = 12.420(3) ?, c = 12.955(3) ?, α = 115.021(5)°, β = 95.544(5)°, and γ = 101.575(5)°. Complex 2 crystallizes in the monoclinic system, space group P21/c, formula CrC18H16N7O4 with a = 11.7171(9) ?, b = 9.4999(7) ?, c = 16.8799(13) ?, and β = 97.449(2)°. Both complexes exhibit distorted octahedral coordination environment with four nitrogen atoms of bpb2− situated at the equatorial plane (Cr–N bond distances range from 1.961(3) to 2.1088(15) ?), and the remaining two trans-positions occupied by terminal ligands H2O/HO and H2O/N3 in 1 and 2, respectively. It is noteworthy that a hydrogen-bonded folded ladder-like structure involving twelve O atoms in 1 and a chair-like hexagonal hydrogen-bonded cluster containing six O atoms are formed. |
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Keywords: | 1 2-Bis(pyridine-2-carboxamido)benzenate chromium(III) complexes crystal structure azide hydroxyl group supramolecular assembly |
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