Synthesis and Crystal Structures of Copper(II) Complexes Derived from 5-Methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenolate and (2-Morpholin-4-ylethyl)-(1-pyridin-2-ylethylidene)amine期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Synthesis and Crystal Structures of Copper(II) Complexes Derived from 5-Methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenolate and (2-Morpholin-4-ylethyl)-(1-pyridin-2-ylethylidene)amine

Authors:	Zhi-Xi Hang Bo Dong Xing-Wen Wang

Institution:	(1) College of Biological and Chemical Engineering, Anhui Polytechnic University, Wuhu, 241000, People’s Republic of China;(2) College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, People’s Republic of China;(3) Department of Biological and Environmental Engineering, Hefei University, Hefei, 230022, People’s Republic of China

Abstract:	Abstract A pair of copper(II) complexes, CuL¹(ONO₂)(OH₂)] 1 and CuBrL²N₃] 2, where L¹ is 5-methoxy-2-(2-morpholin-4-ylethylimino)methyl]phenolate, and L² is (2-morpholin-4-ylethyl)-(1-pyridin-2-ylethylidene)amine, have been synthesized and characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. Complex 1 crystallizes in the monoclinic space group P2₁/c, with a = 10.496(2), b = 19.113(3), c = 8.586(2) ?, β = 105.186(10)°. Complex 2 crystallizes in the monoclinic space group C2/c, with a = 16.606(3), b = 7.357(2), c = 26.043(5) ?, β = 94.996(2)°. The Cu atom in each complex is five-coordinate in a square pyramidal geometry.

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