Crystal structure of Pt(S2COEt)2 |
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| Authors: | Robin D Rogers Michael J Adrowski Andrew H Bond |
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| Institution: | (1) Department of Chemistry, Northern Illinois University, 60115 DeKalb, IL |
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| Abstract: | The crystals of Pt(S2COEt)2 are orthorhombic, Pbca, with (at 20°C)a=7.799(3),b=7.368(6),c=20.588(7) Å.D
cale=2.46g cm–3 forZ=4. The platinum atom resides on a crystallographic center of inversion and is bound to the four sulfur atoms of the xanthato ligand in a square planar geometry. The Pt–S distances are 2.313(6) and 2.320(7)Å with an intraligand S–Pt–S angle of 75.1(2)°. |
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| Keywords: | Crystal structure platinum xanthate square planar |
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