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Preparation and optical properties of silicate glasses containing Pd nanoparticles
Authors:Huidan Zeng  Yuxia Yang  Xiongwei Jiang  Guorong Chen  Jianrong Qiu  Fuxi Gan
Institution:

aKey Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China

bPhoton Craft Project, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, and Japan Science and Technology Agency, Shanghai 201800, China

Abstract:We report the space selective precipitation of Pd nanoparticles in Pd2+-doped silicate glass by ultrashort laser pulses irradiation and further annealing. Absorption spectra, transmission electron microscopy, refractive index measurement and Z-scan technique demonstrated that metallic Pd nanoparticles were precipitated in the glass sample after irradiation by an 800-nm femtosecond laser and subsequent annealing at 600 °C. We discuss a refractive index change and nonlinear absorption that combines the precipitation of Pd nanoparticles.
Keywords:A1  Absorption  B1  Glasses  B1  Pd nanoparticles  B2  Nonlinear optical materials  B3  Femtosecond lasers
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