| KMnO4与醇类有机物制备MnOOH的研究 |
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| 引用本文： | 解利昕,赵煜,陈小棉,王世昌.KMnO4与醇类有机物制备MnOOH的研究[J].人工晶体学报,2012,41(3):652-655. |
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| 作者姓名： | 解利昕 赵煜 陈小棉 王世昌 |
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| 作者单位： | 天津大学化工学院天津市膜科学与海水淡化技术重点实验室,天津,300072 |
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| 摘 要： | 在140℃的条件下,用KMnO4分别与甲醇、乙醇、丙醇、丁醇、乙二醇、1,3-丙二醇以及1,4-丁二醇进行水热反应24 h。采用X射线粉末衍射(XRD)与环境扫描电子显微镜(SEM)对反应产物进行表征。结果表明,KMnO4与乙醇、丙醇、丁醇以及1,4-丁二醇反应均可以得到较纯的棒状MnOOH晶体。KMnO4与甲醇、1,3-丙二醇反应不仅得到了MnOOH晶体并且也得到Mn3O4晶体,而与乙二醇的反应只得到了Mn3O4晶体。并简单探讨了形成这种规律的原因。
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| 关 键 词： | MnOOH晶体 Mn3O4晶体 水热法 |
Preparation of MnOOH from KMnO4 and Hydroxyl Compounds |
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| XIE Li-xin
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ZHAO Yu
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CHEN Xiao-mian
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WANG Shi-chang.Preparation of MnOOH from KMnO4 and Hydroxyl Compounds[J].Journal of Synthetic Crystals,2012,41(3):652-655. |
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| Authors: | XIE Li-xin ZHAO Yu CHEN Xiao-mian WANG Shi-chang |
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| Institution: | (Tianjin Key Laboratory of Membrane Science and Desalination Technology, School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China) |
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| Abstract: | KMnO4 reacts with methanol,ethanol,1-propanol,1-butanol,glycol,1,3-propandiol and 1,4-butandiol for 24 h respectively at 140 ℃ via hydrothermal method.The product was characterized by X-ray powder diffraction and scanning electron microscopy.The result showed that when KMnO4 reacts with ethanol,1-propanol,1-butanol and 1,4-butandiol respectively,the products are rod-like MnOOH crystal,and when KMnO4 reacts with methanol and 1,3-propandiol respectively,the products are MnOOH crystal and Mn3O4 crystal,and when KMnO4 reacts with glycol,the products are Mn3O4.Furthermore,the cause of the result was briefly discussed. |
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| Keywords: | MnOOH crystal Mn3O4 crystal hydrothermal method |
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