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一维Fe_2O_3/α-MoO_3异质结的制备及其可见光光催化性能
引用本文:甄延忠,王杰,王丹军,付峰,李静,薛岗林.一维Fe_2O_3/α-MoO_3异质结的制备及其可见光光催化性能[J].人工晶体学报,2017(1):55-62.
作者姓名:甄延忠  王杰  王丹军  付峰  李静  薛岗林
作者单位:1. 延安大学,陕西省化学反应工程重点实验室,延安716000;2. 西北大学化学与材料科学学院,合成与天然功能分子化学教育部重点实验室,西安710069
基金项目:国家自然科学基金(21406188),陕西省科技攻关项目(2015GY174),陕西省教育厅自然科学基金(14Jk1831),科技成果转化与推广计划项目(2016CGZH-12-01)择优支持
摘    要:利用沉积法获得了一维Fe_2O_3/α-MoO_3异质结光催化剂,通过XRD、SEM-EDS、STEM、XPS、UV-Vis-DRS等测试手段对其组成、形貌、光吸收性质进行了表征,同时在可见光区测试了光催化氧化降解罗丹明B溶液的性能。测试结果表明,Fe_2O_3修饰一维α-MoO_3纳米带可将其光响应扩展至可见光区域,提高光催化性能。1wt%Fe_2O_3/α-MoO_3异质结作为光催化剂时,光照40 min后罗丹明B降解率可达到99%,分别是纯α-MoO_3纳米带和纯Fe_2O_3的光催化活性的3.8倍和26倍。

关 键 词:Fe2  O3  α-MoO3  异质结  可见光催化剂

Preparation and Visible-light Photocatalytic Properties of One Dimensional Fe2 O3/α-MoO3 Heterostructures
ZHEN Yan-zhong,WANG Jie,WANG Dan-jun,FU Feng,LI Jing,XUE Gang-lin.Preparation and Visible-light Photocatalytic Properties of One Dimensional Fe2 O3/α-MoO3 Heterostructures[J].Journal of Synthetic Crystals,2017(1):55-62.
Authors:ZHEN Yan-zhong  WANG Jie  WANG Dan-jun  FU Feng  LI Jing  XUE Gang-lin
Abstract:One Dimension ( 1D ) heterostructure photocatalyst Fe2 O3/α-MoO3 was fabricated by depositional method, which its composition, morphology and photo-adsorption properties of were characterized by XRD、SEM-EDS、STEM、XPS、UV-Vis-DRS, as so as, the performance of photocatalytic degradation RhB was also explored. The test results show that the Fe2 O3 modification not only broaden the absorption spectrum of α-MoO3 nanobelt to the visible light region, but also increase the photocatalytic activity. The optimum photocatalytic activity of MoO3 at Fe2 O3 weight content of 1% could reach 99%after visible light irradiation 40 minutes, which is almost 3. 8 and 26 times as high as that of the pure MoO3 nanobelts and Fe2 O3 .
Keywords:Fe2 O3  α-MoO3  heterostructure  visible-light photocatalysis
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