Dissolution and growth of spinel crystals in a borosilicate glass |
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Authors: | J AltonTJ Plaisted P Hrma |
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Institution: | Pacific Northwest National Laboratory, P.O. Box 999, MS K6-24, Richland, WA 99352, USA |
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Abstract: | The rate of dissolution and growth of settling crystals of spinel was measured optically in a borosilicate melt that was pre-heated at a temperature above liquidus to erase the effects of previous history. The Hixson-Crowell equation, which is based on Fick's first law, was used to determine mass-transfer coefficients (kH) for dissolution and growth; both were found to fit the same Arrhenius function of temperature (T). An attempt was made to estimate the diffusion coefficient (D) and the concentration-boundary-layer thickness (δ). The calculated values of δ compared well with experimental results and observations. The D vs. T function was similar to a literature function obtained for the dissolution of magnetite in sodium disilicate glass. |
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Keywords: | B160 C2863 |
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