| SYNTHESIS OF MESOPOROUS TiO_2 MATERIALS WITH HIGH SPECIFIC AREA USING INORGANIC ACIDS AS CATALYSTS |
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| 作者姓名： | Dan Huang Guangsheng Luo Liming Yang and Yujun Wang The State Key Laboratory of Chemical Engineering |
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| 作者单位： | Dan Huang，Guangsheng Luo，Liming Yang and Yujun Wang The State Key Laboratory of Chemical Engineering，Department of Chemical Engineering，Tsinghua University，Beijing 100084，P. R. China |
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| 摘 要： | This paper presents a synthesis process for preparing mesoporous titanium dioxide materials in the absence of any templates and using inorganic acids as catalysts. Tetrabutyl titanate was used as the precursor at ambient temperature, and four different inorganic acids, i.e., hydrochloric, nitric, sulfuric and phosphoric, were used as catalysts. The as-prepared mesoporous TiO2 materials were characterized by SEM, XRD and nitrogen adsorption/desorption measurements. The influences of different inorganic acids on the properties of TiO2 were discussed and compared in details. Experiments showed that the inorganic acids have significant effects on the surface area, pore volume, pore size, and pore size distribution of the products. The mesoporous TiO2 materials catalyzed by phosphoric acid exhibited the largest specific surface area and largest pore volume with narrow pore size distribution. Vacuum and infrared drying methods tested in the process were found to have subtle impact on the structure of the TiO2 materials prepared.
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SYNTHESIS OF MESOPOROUS TiO2 MATERIALS WITH HIGH SPECIFIC AREA USING INORGANIC ACIDS AS CATALYSTS |
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| Dan Huang,Guangsheng Luo,Liming Yang and Yujun Wang The State Key Laboratory of Chemical Engineering,.SYNTHESIS OF MESOPOROUS TiO_2 MATERIALS WITH HIGH SPECIFIC AREA USING INORGANIC ACIDS AS CATALYSTS[J].China Particuology,2005,3(3). |
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| Authors: | Dan Huang Guangsheng Luo Liming Yang and Yujun Wang The State Key Laboratory of Chemical Engineering |
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| Institution: | Dan Huang,Guangsheng Luo,Liming Yang and Yujun Wang The State Key Laboratory of Chemical Engineering,Department of Chemical Engineering,Tsinghua University,Beijing 100084,P. R. China |
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| Abstract: | This paper presents a synthesis process for preparing mesoporous titanium dioxide materials in the absence of any templates and using inorganic acids as catalysts. Tetrabutyl titanate was used as the precursor at ambient temperature, and four different inorganic acids, i.e., hydrochloric, nitric, sulfuric and phosphoric, were used as catalysts. The as-prepared mesoporous TiO2 materials were characterized by SEM, XRD and nitrogen adsorption/desorption measurements. The influences of different inorganic acids on the properties of TiO2 were discussed and compared in details. Experiments showed that the inorganic acids have significant effects on the surface area, pore volume, pore size, and pore size distribution of the products. The mesoporous TiO2 materials catalyzed by phosphoric acid exhibited the largest specific surface area and largest pore volume with narrow pore size distribution. Vacuum and infrared drying methods tested in the process were found to have subtle impact on the structure of the TiO2 materials prepared. |
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| Keywords: | mesoporous TiO2 inorganic acids infrared drying |
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