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MORPHOLOGY AND ELEMENTAL COMPOSITION OF DUSTFALL PARTICLES INSIDE EMPEROR QIN'S TERRA-COTTA WARRIORS AND HORSES MUSEUM
作者姓名:Tafeng  Hu  Xuxiang  Li  Jungang  Dong  Bo  Rong  Zhenxing  Shen  Junji  Cao  Shun-Cheng  Lee  Judith  C.  Chow  John  G.  Watson
作者单位:[1]Department of Environmental Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, China [2]SKLLQG Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710075, China [3]Emperor Qin's Terra-cotta Warriors and Horses Museum, Xi'an 710054, China [4]Research Center of Urban Environmental Technology and Management, Department of Civil and Structural Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China [5]Division of Atmospheric Sciences, Desert Research Institute, Nevada System of Higher Education, Reno, NV, USA
基金项目:Acknowledgements This research was supported by the National Science Foundation of China (No. 40121303) and was supported by the National Basic Research Program of China (G2004CB720200).
摘    要:Indoor dusffall samples were collected in Pit 1 and Pit 2 of Emperor Qin's Terra-cotta Warriors and Horses Museum in Xi'an, Shaanxi Province, China. The morphological and elemental analysis for long-term (〉10 years) and short-term (~0.5 year) dusffall particles and lacquer pieces on the faces of partly assembled warriors were performed with scanning electron microscopy with energy dispersive X-ray spectrometer (SEM/EDX). The results showed that the majority of dusffall samples appeared to be composed of mineral dust particles, fly ash, and biological particles with different elemental compositions. Most of the mineral particles had irregular shapes with smooth edges. Small floccules of calcium sulfate were more frequently observed in long-term dusffall samples than in short-term samples, implying a progressive chemical reaction between continuous dusffall particles and atmospheric sulfur dioxide. Crystals of calcium sulfate were also found near pits on both inner and outer surfaces of lacquer pieces, revealing an acid chemical reaction between sulfur dioxide and lacquer material as the cause of the formation of erosion pits and cracks on surface of lacquer pieces.

关 键 词:西安  秦始皇陵兵马俑博物馆  室内降尘颗粒物  元素成分  形态学  SEM/EDX
收稿时间:2006-05-11
修稿时间:2006-05-112006-11-19
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