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二甲醚/空气/氩气混合物的爆炸特性
引用本文:高慧会,张博,乔建江,杨少鹏,陈婷,陈潇.二甲醚/空气/氩气混合物的爆炸特性[J].爆炸与冲击,2015,35(5):753-757.
作者姓名:高慧会  张博  乔建江  杨少鹏  陈婷  陈潇
作者单位:1.华东理工大学国家环境保护化工过程环境风险评价与控制重点实验室, 上海 200237
基金项目:爆炸科学与技术国家重点实验室开放基金,中央高校基本科研业务项目
摘    要:在20 L球形爆炸容器中对二甲醚/空气(DME/air)、二甲醚/空气/氩气(DME/air/Ar)混合物在不同初始状态下的爆炸特性进行实验研究,分析了不同初始压力、不同氩气(Ar)稀释浓度对爆炸极限、最大爆炸压力以及最大爆炸压力上升速率的影响。结果表明:DME/air混合物的最大爆炸压力和最大爆炸压力上升速率与DME在混合物中的浓度呈圆顶形关系,最大值出现在DME在混合物中的浓度为6.5%(即最佳当量比, φ=1)附近;初始压力的下降明显降低了DME/air混合物的爆炸上限,但对于其爆炸下限影响不显著;Ar的稀释对富燃DME/air混合物的最大爆炸压力和最大爆炸压力上升速率有显著的惰化作用,但对于贫燃DME/air混合物,最大爆炸压力和最大爆炸压力上升速率在一定的Ar稀释浓度范围内出现上升趋势,当Ar的稀释浓度大于20%,这2个爆炸参数值逐渐下降。

关 键 词:爆炸力学    爆炸极限    爆炸容器    二甲醚    氩气    最大爆炸压力    最大爆炸压力上升速率
收稿时间:2014-01-06

Explosion characteristics of dimethyl ether/air/argon mixtures
Institution:1.State Environmental Protection Key Laboratory of Environmental Risk Assessmentand Control on Chemical Process, East China University of Science and Technology, Shanghai 200237, China2.Safety Engeering & Consulting Co. LTD, East China University ofScience and Technology, Shanghai 200237, China
Abstract:Explosion characteristics of dimethyl ether (DME)/air and DME/air/ argon (Ar) mixtures were studied by using a 20-L spherical explosion-containment vessel under different initial conditions. This paper analyzed the effects of different initial conditions (e.g., pressures, Ar dilution) on the explosion parameters including explosion limits, maximum explosion pressure and maximum rise rate of explosion pressure. A dome-shaped relationship was found between maximum explosion pressure and DME concentration. And there lies a dome-shaped relationship between maximum explosion pressure rise rate and DME concentration. Their maximum values appear in the vicinity of the stoichiometric composition. Lowering the initial pressure can significantly decrease the upper flammability limit, but has no influence on the lower explosion limit. For fuel-rich DME/air mixtures, Ar dilution can greatly decrease the maximum explosion pressure and the maximum rise rate of explosion pressure. For fuel-lean ones, in a certain range of Ar concentration, the maximum explosion pressure and the maximum rise rate of explosion pressure increase with the increasing of Ar concentration. And these explosion parameters decrease eventually with the increasing of Ar concentration over 20%.
Keywords:mechanics of explosion  explosion limits  explosion-containment vessel  dimethyl ether (DME)  argon  maximum explosion pressure  maximum rate of pressure rise
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