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低温沉积Ag-Cu薄膜的耐原子氧和摩擦学性能
引用本文:高晓明,孙嘉奕,胡明,翁立军,伏彦龙,杨军,谭洪根,张良俊.低温沉积Ag-Cu薄膜的耐原子氧和摩擦学性能[J].摩擦学学报,2013,33(3):245-252.
作者姓名:高晓明  孙嘉奕  胡明  翁立军  伏彦龙  杨军  谭洪根  张良俊
作者单位:1. 上海市空间飞行器机构重点实验室,上海201108;中国科学院兰州化学物理研究所固体润滑国家重点实验室,甘肃兰州730000
2. 中国科学院兰州化学物理研究所固体润滑国家重点实验室,甘肃兰州,730000
3. 上海市空间飞行器机构重点实验室,上海,201108
基金项目:国家自然科学基金项目(50301015,51227804))资助.
摘    要:采用多弧离子镀在低温(173 K)沉积了Ag-Cu薄膜,通过地面原子氧模拟试验机构考察了薄膜的耐原子氧性能,通过X射线衍射(XRD)、原子力显微镜(AFM)和球-盘摩擦试验机对薄膜结构、耐原子氧性能和摩擦学性能进行了表征,并与室温(300 K)及低温(173 K)沉积Ag薄膜进行了比较研究.结果表明:低温沉积Ag-Cu薄膜由面心立方结构的AgCu合金相和少量Ag或Cu组成,Cu元素合金和低温沉积可细化Ag薄膜的晶畴尺寸、提高其致密性,细密的薄膜结构有利于抑制原子氧对薄膜的攻击,因此低温沉积的Ag-Cu薄膜表现出较好的耐原子氧性能;磨损试验结果表明低温沉积的Ag-Cu薄膜表现出较好的耐磨性,这主要归因于其细密的薄膜结构和较高的膜-基结合强度,此外由于其耐原子氧性能的改善,低温沉积Ag-Cu薄膜在原子氧辐照前后磨损率的增加明显低于低温和室温沉积Ag薄膜.

关 键 词:低温沉积  Ag-Cu薄膜  耐原子氧性能  摩擦学性能

Atomic Oxygen Resistant and Wear Behavior of Ag-Cu Films Deposited at a Low Temperature
GAO Xiao-ming,SUN Jia-yi,HU Ming,WENG Li-jun,FU Yan-long,YANG Jun,TAN Hong-gen and ZHANG Liang-jun.Atomic Oxygen Resistant and Wear Behavior of Ag-Cu Films Deposited at a Low Temperature[J].Tribology,2013,33(3):245-252.
Authors:GAO Xiao-ming  SUN Jia-yi  HU Ming  WENG Li-jun  FU Yan-long  YANG Jun  TAN Hong-gen and ZHANG Liang-jun
Institution:1. Shanghai Key Laboratory of Spacecraft Mechanisms, Shanghai 201108, China;2. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;Shanghai Key Laboratory of Spacecraft Mechanisms, Shanghai 201108, China;Shanghai Key Laboratory of Spacecraft Mechanisms, Shanghai 201108, China
Abstract:Ag-Cu films were deposited at a low temperature (173 K, LT-Ag-Cu films) by arc ion plating. Atomic oxygen (AO) irradiation experiments were conducted using a ground AO simulation facility. The AO resistant and wear behavior of the LT-Ag-Cu films were investigated by X-ray diffraction, atomic force microscope and a ball-on-disk tribometer using Ag film deposited at room temperature (300 K, RT-Ag film) as a reference. The results show that the LT-Ag-Cu films were composed of AgCu alloy and small amount of Ag or Cu. Because of densified microstructure, lower crystallite size and alloying with Cu, the LT-Ag-Cu film represented much better anti-oxidation capability under the AO irradiation condition than that of the RT- and LT-Ag films. Wear results show that as compared with the RT-Ag film, the LT-Ag-Cu films exhibited much better wear resistance due to the better film-substrate adhesion as well as the fine/dense structure, and the wear increase resulted from the AO irradiation was much lower for the LT-Ag-Cu films than the RT- and LT-Ag film due to the improvement in the AO resistant behavior.
Keywords:low temperature deposition  Ag-Cu films  AO resistant behavior  wear
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