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胍盐离子液体对钢/铝摩擦副的摩擦性能研究
引用本文:于桂琴,刘建军,梁永民.胍盐离子液体对钢/铝摩擦副的摩擦性能研究[J].摩擦学学报,2015,35(1):96-101.
作者姓名:于桂琴  刘建军  梁永民
作者单位:兰州大学化学化工学院,甘肃兰州,730000
基金项目:中央高校基本科研业务费专项资金(lzujbky-2013-181)和甘肃省青年科技基金计划(145RJYA236)资助.
摘    要:合成了两种胍盐离子液体,采用热重分析仪评价其热稳定性.利用SRV往复摩擦试验机测试了离子液体的摩擦学性能并与常规离子液体和液体石蜡进行了对比.利用扫描电子显微镜观察磨斑处的形貌并用X射线光电子能谱仪表征了磨斑表面的化学状态,并对润滑机理进行了分析.结果表明:胍盐离子液体对钢/铝摩擦副具有优异的摩擦学性能;摩擦过程中,钢/铝摩擦副界面发生了复杂的摩擦化学反应并形成了边界润滑膜.

关 键 词:胍盐离子液体  摩擦学性能  钢/铝摩擦副

Tribological Investigation of Guanidinium Ionic Liquids as Lubricants for Steel /Al Contacts
YU Gui-qin , LIU Jian-jun , LIANG Yong-min.Tribological Investigation of Guanidinium Ionic Liquids as Lubricants for Steel /Al Contacts[J].Tribology,2015,35(1):96-101.
Authors:YU Gui-qin  LIU Jian-jun  LIANG Yong-min
Institution:College of Chemistry and Engineering, Lanzhou University, Lanzhou 730000, China;College of Chemistry and Engineering, Lanzhou University, Lanzhou 730000, China;College of Chemistry and Engineering, Lanzhou University, Lanzhou 730000, China
Abstract:Two kinds of guanidinium ionic liquids were synthesized. The thermal stabilities of the ionic liquids were evaluated by a hermogravimetric analyzer. Their tribological properties were investigated and compared with alkyl imidazole ionic liquids and liquid paraffin by SRV friction-wear test. The results show that guanidinium ionic liquids were the best lubricant among the tested lubricants for steel/Al contacts. The images of worn surface were observed using scanning electron microscope. The X-ray photoelectron spectrometer analysis was carried out to explore the lubrication mechanism. The results show that complex tribochemical reactions occurred and the boundary lubrication films were formed in aluminum/steel friction pair interface during the sliding process.
Keywords:guanidinium ionic liquids  tribological properties  steel/Al contacts
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