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摩擦-电化学噪声法研究Mo改性钛合金的腐蚀-磨损行为
引用本文:张敏,马永,张翔宇,范爱兰,唐宾.摩擦-电化学噪声法研究Mo改性钛合金的腐蚀-磨损行为[J].摩擦学学报,2012,32(3):301-305.
作者姓名:张敏  马永  张翔宇  范爱兰  唐宾
作者单位:太原理工大学表面工程研究所,太原,030024
基金项目:The project was supported by the National Natural Science Foundation of China(51171125),the Science and Research Projects of Shanxi Province, China(20110321051) Shanxi Province Scientific Research Project for Returning Students and School Development Technology Fund of Taiyuan University of Technology 国家自然科学基金项目(51171125)、山西省科技攻关项目(20110321051)、山西省回国留学人员科研项目(2011-038)和太原理工大学校发展科技基金(K201015)资助.
摘    要:利用等离子表面改性技术在Ti6Al4V合金基体上制备Mo渗镀复合改性层,考察改性层组织结构,利用微动摩擦学试验机并结合电化学噪声技术对比研究基材及改性层在0.5 mol/L NaCl溶液中的腐蚀-微动摩擦学行为,对腐蚀-摩擦过程中的噪声参数进行分析.结果表明:纯Mo改性层能够明显改善钛合金的耐磨和减摩特性;同时提高了合金在0.5 mol/L NaCl溶液中的自腐蚀电位及降低了腐蚀电流,改善了合金表面的腐蚀-摩擦学性能.

关 键 词:钛合金  Mo改性层  微动摩擦  腐蚀-磨损性能  电化学噪声
修稿时间:1/5/2012 12:00:00 AM

Corrosive-Wear Behavior of Mo Modified Ti6Al4V Alloy by Wear-Electrochemical Noise Method
ZHANG Min,MA Yong,ZHANG Xiang-yu,FAN Ai-lan and TANG Bin.Corrosive-Wear Behavior of Mo Modified Ti6Al4V Alloy by Wear-Electrochemical Noise Method[J].Tribology,2012,32(3):301-305.
Authors:ZHANG Min  MA Yong  ZHANG Xiang-yu  FAN Ai-lan and TANG Bin
Institution:Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, China;Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, China;Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, China;Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, China;Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Abstract:The Mo surface modified layer on Ti6Al4V substrate is obtained by plasma surface alloying. The structure and composition of the Mo surface modified layer are investigated by X-ray diffraction (XRD) and glow discharge optical emission spectroscopy. The duplex Mo modified layer contains a pure Mo coating on subsurface and diffusion layers between the subsurface and substrate. XRD analysis of the Mo modified layer reveals that a Mo phase exists in the modified layer with <110> and <211> orientations in the subsurface. Corrosion-wear behaviors of Ti6Al4V substrate and Mo modified Ti6Al4V alloy sliding against corundum are investigated with the wear-electrochemical noise technique in a 0.5mol/L NaCl solution. Results indicate that the Mo modified layer improves the antiwear and friction reduction properties of Ti6Al4V. Moreover, the Mo modified layer improves self-corroding electric potentials and decrease the current of Ti6Al4V. The Mo modified layer can improve the corrosion-wear behavior of Ti6Al4V.
Keywords:Ti6Al4V  Mo modified layer  fretting friction  corrosion-wear behavior  electrochemical noise
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