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水溶性纳米铜的制备及其摩擦学性能研究
引用本文:许耀华,杨广彬,张晟卯,张平余,张治军.水溶性纳米铜的制备及其摩擦学性能研究[J].摩擦学学报,2012,32(2):165-170.
作者姓名:许耀华  杨广彬  张晟卯  张平余  张治军
作者单位:1. 河南大学特种功能材料教育部重点实验室,河南开封,475004
2. 河南大学特种功能材料教育部重点实验室,河南开封475004/中国科学院兰州化学物理研究所固体润滑国家重点实验室,甘肃兰州730000
基金项目:国家自然科学基金(50975077)和固体润滑国家重点实验室开放基金(1003)资助.
摘    要:以氨基功能化羟基硅酸镁为修饰剂,采用原位表面修饰方法制备了水溶性Cu纳米微粒.利用透射电子显微镜观察了水溶性Cu纳米微粒的形貌,利用导热系数测定仪测定了水溶性纳米Cu分散液的导热系数,并通过SRV往复摩擦磨损试验机(球-盘接触方式)考察了水溶性Cu纳米微粒作为水基添加剂的摩擦学性能.结果表明:水溶性纳米Cu微粒作为水基添加剂能够显著减小钢-钢摩擦副的摩擦系数和磨损率,提高纯水的承载能力;在合适的浓度下,水溶性纳米Cu微粒可使纯水导热系数提高近10%.

关 键 词:水溶性纳米Cu  水基添加剂  制备  摩擦学性能

Preparation of Water-soluble Copper Nanoparticles and Evaluation of Their Tribological Properties
XU Yao-hu,YANG Guang-bin,ZHANG Sheng-mao,ZHANG Ping-yu and ZHANG Zhi-jun.Preparation of Water-soluble Copper Nanoparticles and Evaluation of Their Tribological Properties[J].Tribology,2012,32(2):165-170.
Authors:XU Yao-hu  YANG Guang-bin  ZHANG Sheng-mao  ZHANG Ping-yu and ZHANG Zhi-jun
Institution:Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004, China;Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004, China;1. Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004, China; 2. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004, China;Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004, China
Abstract:Water soluble Cu nanoparticles are synthesized by in situ surface modification with NH2-functionalized magnesium silicate hydroxide and characterized.The morphology of as-prepared Cu nanoparticles is observed on a transmission electron microscope.The conductivity coefficient of the aqueous solution of Cu nanoparticles is measured with a thermal conductivity coefficient surveying instrument.An Optimol SRV Ⅳ(ball-on-block) oscillating friction and wear tester and is performed to evaluate the tribological properties of Cu nanoparticles in water.Results indicate that as-prepared Cu nanoparticles have good friction-reducing and anti-wear properties for steel-steel frictional pair.In the meantime,as-prepared Cu nanoparticles can reduce the conductivity coefficient of pure water by nearly 10%,which is beneficial for as-prepared Cu nanoparticles to function as a kind of water-based lubricating additives.
Keywords:water soluble Cu nanoparticle  water-based additive  preparation  tribological property
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