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构造本构方程的另一种方法——非平衡不可逆热力学方法
引用本文:宋道云,刘洪来,方波,江体乾.构造本构方程的另一种方法——非平衡不可逆热力学方法[J].力学与实践,2002,24(3):27-29.
作者姓名:宋道云  刘洪来  方波  江体乾
作者单位:1. 华东理工大学化工所流变学研究室,上海,200237
2. 华东理工大学物理化学研究室,上海,200237
摘    要:重点介绍了以Onsager-Casimir倒易定律为基础,从不可逆热力学观点出发,对远离平衡状态,引进新的变量(被称为动态变量),构造本构方程.并以简单剪切流场为例,求出了测黏函数.

关 键 词:不可逆非平衡热力学  Onsager-Casimir倒易定律  动态变量
修稿时间:2001年4月20日

A NEW METHOD OF DEVELOPING CONSTITUTIVE EQUATIONS WITH NON-EQUILIBRIUM IRREVERSIBLE THERMODYNAMICS
SONG Daoyun LIU Honglai FANG BoJIANG TiqianRheology Research Center,East China University ofScience and Technology,Shanghai ,ChinaPhysical Chemistry Research Division,East ChinaUniversity of Science and Technology,Shanghai ,China.A NEW METHOD OF DEVELOPING CONSTITUTIVE EQUATIONS WITH NON-EQUILIBRIUM IRREVERSIBLE THERMODYNAMICS[J].Mechanics and Engineering,2002,24(3):27-29.
Authors:SONG Daoyun LIU Honglai FANG BoJIANG TiqianRheology Research Center  East China University ofScience and Technology  Shanghai  ChinaPhysical Chemistry Research Division  East ChinaUniversity of Science and Technology  Shanghai  China
Institution:SONG Daoyun LIU Honglai FANG BoJIANG TiqianRheology Research Center,East China University ofScience and Technology,Shanghai 200237,ChinaPhysical Chemistry Research Division,East ChinaUniversity of Science and Technology,Shanghai 200237,China
Abstract:In this paper, some traditional methodsof developing constitutive equations are reviewedbriefly We concentrate on the irreversible thermo-dynamics and the dynamics variables based on theOnsager-Casimir reciprocal law to develop the rhe-ological equations. In the end, a simple shear fieldis used as an example to get the material functions.
Keywords:non-equilibrium irreversible thermody-namics  Onsager-Casimir reciprocal law  dynamicsvariable
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