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Low-temperature growth of ZnO epitaxial films by metal organic chemical vapor deposition
Authors:Email author" target="_blank">BP?ZhangEmail author  NT?Binh  K?Wakatsuki  N?Usami  Y?Segawa
Institution:(1) Photodynamics Research Center, The Institute of Physical and Chemical Research, RIKEN, 519-1399 Aoba, Aramaki, Aoba-ku, 980–0845 Sendai, Japan;(2) Department of Physics, Graduate School of Science, Tohoku University, 980-8578 Sendai, Japan;(3) Institute for Materials Research, Tohoku University, 980-8577 Sendai, Japan
Abstract:ZnO films were grown on Al2O3 (0001) substrates by metal organic chemical vapor deposition at temperatures of Tg=150sim300 °C. Epitaxial growth was obtained for Tgge200 °C. The in-plane orientation of the ZnO unit cells was found to change from a no-twist one with respect to that of the substrate at Tg=200 °C to a 30°-twist one at Tg=300 °C. Absorption and photoluminescence were observed from the film grown at 150 °C, although there was no evidence of epitaxial growth. Films grown at Tgle200 °C exhibited smoother surfaces. Moreover, all the films grown at Tg=150sim300 °C revealed acceptor-related emission peaks, indicating the incorporation of acceptors into the films. PACS 81.15.Gh; 78.55.Et; 78.66.Hf
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