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Room-temperature deposition of transparent conductive Al-doped ZnO thin films using low energy ion bombardment
Authors:C G Jin  T Yu  Z F Wu  F Wang  M Z Wu  Y Y Wang  Y M Yu  L J Zhuge and X M Wu
Institution:(1) Department of Physics, Soochow University, Soochow, 215006, China;(2) The Key Laboratory of Thin Films of Jiangsu, Soochow University, Soochow, 215006, China;(3) Yancheng Institute of Technology, Yancheng, 224003, China;(4) Wenzheng College of Soochow University, Soochow, 215006, China;(5) Analysis and Testing Center, Soochow University, Soochow, 215006, China;
Abstract:Al-doped zinc oxide (AZO) films are prepared on quartz substrates by dual-ion-beam sputtering deposition at room temperature (∼25°C). An assisting argon ion beam (ion energy E i =0–300 eV) directly bombards the substrate surface to modify the properties of AZO films. The effects of assisted-ion beam energy on the characteristics of AZO films were investigated in terms of X-ray diffraction, atomic force microscopy, Raman spectra, Hall measurement and optical transmittance. With increasing assisting-ion beam bombardment, AZO films have a strong improved crystalline quality and increased radiation damage such as oxygen vacancies and zinc interstitials. The lowest resistivity of 4.9×10−3Ω cm and highest transmittance of above 85% in the visible region were obtained under the assisting-ion beam energy 200 eV. It was found that the bandgap of AZO films increased from 3.37 to 3.59 eV when the assisting-ion beam energy increased from 0 to 300 eV.
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