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Optical emission diagnostics of laser-induced plasma for diamond-like film deposition
Authors:X Chen  J Mazumder  A Purohit
Institution:(1) Laser-Aided Materials Processing Laboratory, Department of Mechanical and Industrial Engineering, University of Illinois at Urbana-Champaign, 61801 Urbana, IL, USA;(2) Engineering Physics Division, Argonne National Laboratory, 60439 Argonne, IL, USA
Abstract:Optical emission from a laser-induced plasma plume is recorded during KrF excimer laser ablation of graphite in a gas mixture of Ar and H2 (3%) for deposition of diamond-like thin films. At sub-GW/cm2 laser intensities the spectrum is dominated by the bands of C2 and CN. From the band intensities, the vibrational temperatures of both radicals are calculated to be 12–15×103 K, and their concentrations are estimated to be 5×1014 cm–3 and 2×1014 cm–3, respectively.
Keywords:81  60 Z  81  15 Z  33  52
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