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Enhancement of luminescence properties of Eu:YVO4 in polymeric nanocomposites upon UV excitation
Authors:D Hreniak  J Doskocz  R Lisiecki  N Vu  TK Anh  A Speghini
Institution:a Institute of Low Temperature and Structure Research, PAS, ul. Okolna 2, PL-50-422 Wroclaw, Poland
b Institute of Materials Science, VAST, 18 Hoang-Quoc-Viet, Hanoi, Vietnam
c Laboratorio di Chimica dello Stato Solido, Dipartimento di Biotecnologie, University of Verona, Strada Le Grazie 15, I-37134 Verona, Italy
Abstract:Highly emissive Eu3+:YVO4 nanocrystals were successfully prepared by the hydrothermal method. The average diameter of grains was determined to be 15 nm. Transparent polymer nanocomposites composed of PMMA and well dispersed Eu3+:YVO4 nanocrystals were fabricated by in situ polymerization. The nanocrystalline powders and nanocomposites were characterized by scanning and transmission electron microscopy (TEM) and X-ray diffraction (XRD). The luminescence properties of the obtained nanocomposites were investigated and compared with the starting powders and Eu3+:YVO4 single crystal. The effect of the polymeric host on the luminescence properties of Eu3+:YVO4 is presented and discussed.
Keywords:Nanocrystals  YVO4  Europium  Size-effects  Nanocomposite
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