On heat diffusion mode of structural phase transition by two-fluid model

With the help of the two-fluid model developed by Götze and Michel for phonons it is shown for a simple model Hamiltonian that in the low temperature phase the optical soft mode becomes isothermal, the heat diffusion mode is dominant near the transition temperatureT _c and the quasiparticle interaction is of great importance in determining the thermodynamic quantities nearT _c. Green function techniques are applied to describe the two-fluid model functions in a microscopic way. The simplest approximations are discussed for the model equations describing nonequilibrium phenomena of the soft optical phonon mode in the low temperature phase. The quasiparticle interaction operator can be related to the interaction operator between quasiparticles and the condensed mode. This relation enables one to understand the behaviour of the thermodynamic quantities near the transition temperature on a microscopic way. The first order displacive phase transition is also discussed.