Microstructure and morphology of electrodeposited Ni-P alloys treated by high energy surface mechanical attrition |
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Authors: | Ádám Révész László PéterPéter J Szabó Péter SzommerImre Bakonyi |
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Institution: | a Department of Materials Physics, Eötvös University, Budapest, H-1518, P.O.B. 32, Budapest, Hungary b Research Institute for Solid State Physics and Optics, Hungarian Academy of Sciences, H-1525, Budapest, P.O.B. 49, Hungary c Department of Materials Science and Engineering, University of Technology and Economy, Budapest, H-1111, Hungary |
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Abstract: | Fully amorphous Ni-P layer electrodeposited onto a Cu plate was subjected to severe plastic deformation using surface mechanical attrition treatment in a high energy SPEX 8000 shaker mill. Two series of experiments using different milling conditions (series I: 20 6.35-mm balls; series II: 100 1.59-mm balls) were carried out to explore the mechanism of the process and to investigate the structure of the developed coatings. The evolution of the microstructure and mechanical properties of the Ni-P layer after the deformation process was studied by x-ray diffraction, scanning electronmicroscopy and hardness measurements. We demonstrate that the different mechanical treatments controllably influence the mechanical behavior of the Ni-P metallic glass coating. When the vial of the mill is loaded with larger balls, deformation-induced Ni3P compound particles form in the amorphous matrix resulting in a hard (HV = 17 GPa) but non-uniform coating. In the case of milling with many small balls, the increase in the surface hardness is considerably lower (7 GPa) as a consequence of reduced impact energy. |
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Keywords: | Coatings Abrasion Surface properties Hardness |
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