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The influence of annealing temperature and tellurium (Te) on electrical and dielectrical properties of Al/p-CIGSeTe/Mo Schottky diodes
Authors:S Fiat  İ Polat  E Bacaksiz  M Kompitsas  G Çankaya
Institution:1. Gaziosmanpa?a University, Faculty of Arts and Sciences, Physics Department, 60240 Tokat, Turkey;2. Karadeniz Teknik University, Faculty of Arts and Sciences, Physics Department, 61080 Trabzon, Turkey;3. National Hellenic Research Foundation, Theoretical and Physical Chemistry Institute, 11635 Athens, Greece;4. Y?ld?r?m Beyaz?t University, Faculty of Engineering and Natural Sciences, Materials Engineering, 06030 Ulus, Ankara, Turkey;5. Kastamonu University, Faculty of Engineering and Architecture, Materials Science and Engineering, 37200 Kastamonu, Turkey
Abstract:p-CuIn0.7Ga0.3(Se(1?x)Tex)2 type thin films were synthesized by thermal evaporation method on Mo coated glass substrates. To obtain Al/CuIn0.7Ga0.3(Se(1?x)Tex)2/Mo Schottky diode structure for two compositions of x = 0.0 and 0.6, Al metal was evaporated on upper surface of CuIn0.7Ga0.3(Se(1?x)Tex)2 as a front contact. Al/p-CuIn0.7Ga0.3(Se(1?x)Tex)2/Mo structures were annealed temperature range from 150 °C to 300 °C for 10 min under vacuum. The electrical and dielectrical properties of Al/p-CuIn0.7Ga0.3(Se(1?x)Tex)2 (CIGSeTe) Schottky barrier diodes (SBD) have been investigated. Capacitance–Voltage (CV) characteristics, Conductance–Voltage (G/wV) characteristics and interface state density were studied in order to obtain electrical and dielectrical parameters. The effects of interface state density (Nss), series resistance (Rs), the dielectric constant (?′), dielectric loss (?″), dielectric loss tangent (tan δ), ac electrical conductivity (σac) and carrier doping densities were calculated from the CV and G/wV measurements and plotted as a function of annealing temperature. It was observed that the values of carrier doping density NA for annealing temperature at 150 °C decreased from 2.83 × 10+15 cm?3 to 2.87 × 10+14 cm?3 with increasing Te content from x = 0.0 to 0.6. The series resistance for x = 0.0 found to be between 10 and 75 Ω and between 50 and 230 Ω for x = 0.6 in the range of annealing temperature at 150–300 °C.
Keywords:CIGSeTe  Chalcopyrite compounds  Electrical properties  Dielectrical properties
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