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Insulator-Metal Transition due to La Doping in Double Perovskite Sr2MnMoO6
作者姓名:刘晓峻  黄巧建  徐胜  张淑仪  罗爱华
作者单位:[1]InstituteofAcousticsandLaboratoryofModernAcoustics,NanjingUniversity,Nanjing210093 [2]DepartmentofCrystallineMaterialsScience,NagoyaUniversityNagoya464-8601,Japan
摘    要:Resistivity, thermal diffusivity, lattice and magnetic properties of double perovskite Sr2-xLaxMnMoO6 are investigated with systematic change of La doping concentration x from 0.0 to 0.4. The insulator to metal phase transition is observed with increasing x above 0.3, suggesting that the extra electrons via substitution of La^3 for Sr^2 ions occupy mainly the conduction Mo-4d band. According to the insulator to metal phase transition, the thermal diffusivity of Sr2-xLaxMnMoO6 enhances from 0.33cm^2/s at x=0.0 to 0.49cm^2/s at x=0.4. We further investigate the La doping effects on the lattice and magnetic properties.

关 键 词:绝缘金属  镧掺杂  钙钛矿结构  热扩散率  电阻系数
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