| Raman and X-Ray Investigation of Pyrope Garnet （Mg0.76Fe0.14Ca0.10）3Al2Si3O12 under High Pressure |
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| 引用本文： | 马艳梅,陈海勇,李雪飞,高玲玲,崔启良,邹广田.Raman and X-Ray Investigation of Pyrope Garnet （Mg0.76Fe0.14Ca0.10）3Al2Si3O12 under High Pressure[J].中国物理快报,2007,24(5):1180-1182. |
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| 作者姓名： | 马艳梅 陈海勇 李雪飞 高玲玲 崔启良 邹广田 |
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| 作者单位： | National Laboratory of Superhard Materials, Jilin University, Changchun 130012 |
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| 基金项目： | Supported by the National Natural Science Foundation of China under Grant No 10299040, and the National Basic Research Programme of China under Grant Nos 2001CB711201 and 2005CB724400. |
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| 摘 要： | The compressional behavlour of natural pyrope garnet is investigated by using angle-dlspersive synchrotron radiation x-ray diffraction and Raman spectroscopy in a diamond anvil cell at room temperature. The pressureinduced phase transition does not occur under given pressure. The equation of state of pyrope garnet is determined under pressure up to 25.3 GPa. The bulk modulus KTO is 199 GPa, with its first pressure derivative K′TO fixed to 4. The Raman spectra of pyrope garnet are studied. A new Raman peak nearly at 743 cm^-1 is observed in a bending vibration of the SiO4 tetrahedra frequency range at pressure of about 28 GPa. We suggest that the new Raman peak results from the lattice distortion of the SiO4 tetrahedra. All the Raman frequencies continuously increase with the increasing pressure. The average pressure derivative of the high frequency modes （650-1000 cm^-1） is larger than that of the low frequency （smaller than 650 cm^-1）. Based on these data, the mode Grǖneisen parameters for pyrope are obtained.
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| 关 键 词： | X射线 辐射作用 榴子石 高压 |
| 收稿时间： | 2006-12-15 |
| 修稿时间： | 2006-12-15 |
Raman and X-Ray Investigation of Pyrope Garnet (Mg 0.76 Fe 0.14 Ca 0.10)3Al2Si3O12 under High Pressure |
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| MA Yan-Mei,CHEN Hai-Yong,LI Xue-Fei,GAO Ling-Ling,CUI Qi-Liang,ZOUGuang-Tian.Raman and X-Ray Investigation of Pyrope Garnet (Mg 0.76 Fe 0.14 Ca 0.10)3Al2Si3O12 under High Pressure[J].Chinese Physics Letters,2007,24(5):1180-1182. |
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| Authors: | MA Yan-Mei CHEN Hai-Yong LI Xue-Fei GAO Ling-Ling CUI Qi-Liang ZOUGuang-Tian |
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| Institution: | National Laboratory of Superhard Materlals, Jilin University, Changchun 130012 |
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| Abstract: | The compressional behaviour of natural pyrope garnet is investigated by using angle-dispersive synchrotron radiation x-ray diffraction and Raman spectroscopy in a diamond anvil cell at room temperature. The pressure-induced phase transition does not occur under given pressure. The equation of state of pyrope garnet is determined under pressure up to 25.3GPa. The bulk modulus KT0 is 199GPa, with its first pressure derivative K'T0 fixed to 4. The Raman spectra of pyrope garnet are studied. A new Raman peak nearly at 743cm-1 is observed in a bending vibration of the SiO4 tetrahedra frequency range at pressure of about 28GPa. We suggest that the new Raman peak results from the lattice distortion of the SiO4 tetrahedra. All the Raman frequencies continuously increase with the increasing pressure. The average pressure derivative of the high frequency modes (650--1000cm-1) is larger than that of the low frequency (smaller than 650cm-1). Based on these data, the mode Gruneisen parameters for pyrope are obtained. |
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| Keywords: | 07 35 +k 61 10 -i 78 30 -j 91 60 Fe |
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