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Synthesis of functionalized diaryl alkanes from azines using Lewis acidic ionic liquids
Authors:A Rajendran  C Karthikeyan
Institution:(1) Department of Chemistry, Sir Theagaraya College, Chennai-21, India
Abstract:Novel Lewis acidic ionic liquids containing thionyl cations and chlorozincate anions were obtained by one pot synthesis for the first time. This ionic liquid is used as catalyst for Friedel–Crafts alkylation of benzalazines and acetophenone azines for the synthesis of substituted diaryl alkanes. The products were characterized by elemental and spectral (FT-IR, 1H-NMR and 13C-NMR) analyses.
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