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A study on LiBOB-based nanocomposite gel polymer electrolytes (NCGPE) for Lithium-ion batteries
Authors:V Aravindan  P Vickraman
Institution:(1) Department of Physics, Gandhigram Rural University, Gandhigram, 624302, India
Abstract:Lithium bis(oxalato)borate (LiBOB) salt-based nanocomposite gel polymer blend electrolyte (PVdF/PVC) membranes have been prepared by solution casting technique for various concentrations of TiO2. The effect of anatase structure of nanosized titanium dioxide in the plasticized PVC/PVdF + LiBOB matrix has been observed in the 2:1 salt filler ratio in the impedance measurements that the conductivity is increased one order of magnitude higher than the filler-free electrolyte (1:0 salt:filler ratio). The phase morphology of this electrolyte membrane represents the appearance of the free volume sites for ionic migration.
Keywords:Polymer electrolytes  Li-ion batteries  Ionic conductivities  SEM  FTIR
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